Earth Sciences Department Theses and Dissertations
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The IUPUI graduate program in Geology leads to a Master of Science degree from Indiana University. Our terminal degree at the IUPUI campus is the Master of Science. As a result, our faculty are able to focus their attention on our Masters program student research. We offer a thesis and non-thesis option; however, typically only thesis-option students are considered for funding. Our thesis option requires 24 credit hours of graduate level courses and 6 credit hours of a research thesis. We have between 8-12 full-time graduate students per year.
Interested students should contact us prior to applying. If applicable, an appointment/visit can be set up for you to see our facilities and meet a few of our faculty. Students can apply with an interest in a specific faculty member or a group of faculty members. Admission decisions are decided by our graduate committee and not individual faculty members. Once you enter the program, you will take a majority of your courses in your first year. Also, you will choose your research advisor and submit your thesis (research) proposal. Your second year (including the summer) is focused on completing your research project and writing your thesis while finishing your course work.
For more information: http://www.geology.iupui.edu/Degree_Programs/Graduate_Studies/index.htm
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Item A 4600-year record of lake level and hydroclimate variability from an eastern Andean lake in Colombia(2016-05) Rudloff, Owen M.; Bird, Broxton Williams; Gilhooly, William, III; Filippelli, Gabriel M.Hydroclimatic variability in the eastern Colombian Andes is examined using a decadally-resolved, multiproxy lake sediment record from Laguna de Ubaque, Colombia. Hydroclimate trends are examined and compared to existing local, regional, and trans-Andean records to enhance existing knowledge of Late Holocene Colombian precipitation and assess potential hydroclimatic forcing mechanisms in tropical South America. Sedimentological analyses, including percent lithics, grain size, C:N and magnetic susceptibility are sensitive to hydroclimate and lake level while charcoal size and concentrations reflect fire variability. Results show that deep lacustrine conditions characterized by laminated deposits were not established until approximately 3500 cal yr B.P., prior to which, terrestrial C:N values and unstructured sediments indicate that drier, marsh-like conditions prevailed. Between 3500 and 2000 cal yr B.P., interrupted only by a 300-year arid interval from 2800 to 2500 cal yr B.P., greatly increased overall clastic deposition indicates a broad precipitation maximum while decreased sand deposition and the preservation of finely laminated sediment indicate deep lake conditions. After 2000 cal yr B.P., decreased clastic deposition suggests reduced precipitation, but the continued accumulation of laminated sediments indicates that conditions were wet enough to fill the basin continuously until the present day. These observations address two of the driving questions of Andean paleoclimate: were the northern and southern Andes in vi phase during the Holocene, or out of phase, and what are the main drivers of Holocene Andean climate? We find that the early part of Ubaque’s record more closely resembles southern Andean precipitation records until 2000 cal yr B.P., at which point it abruptly switches to resemble northern precipitation records. We attribute this to a combination of the southward migration of the intertropical convergence zone (ITCZ), and an increase in eastern Pacific sea surface temperatures (SST). In addition, we find that Colombian hydroclimate records exhibit a bimodal precipitation pattern, which we attribute to their location either on the Andean slopes or in the high interior Andes.Item A Combined Molecular and Isotopic Study of Sulfur Bacteria in Meromictic Lakes of the Pacific Northwest(2023-12) Harris, James H., IV; Gilhooly, William P., III; Druschel, Gregory K.; Bird, Broxton W.The isotope effects that result from the activity of modern sulfur metabolizing bacteria serve as analogs to interpreting the sulfur isotope values preserved in the geologic record. This biogenic signal is vital to reconstructing the history of Earth’s ancient oceans and atmosphere. However, the isotope compositions imprinted by these bacteria were influenced by multiple factors that must be considered when using these values to make interpretations about environmental change. These factors include: (1) sulfate availability, (2) the rapid and quantitative reoxidation of sulfide (i.e., cryptic sulfur cycling), (3) the initial oxygen isotope compositions of sulfate and water, and (4) the taxonomic structure of sulfur-metabolizing bacterial communities. To address these questions, this project studied four permanently stratified, anoxic and sulfidic (euxinic), lakes in southern British Columbia, Canada, and northern Washington, USA, that have a wide range of sulfate concentrations, from 0.15 – 120 mM. This project resulted in six key findings – (1) the measurement of large Δ34SSO4-H2S values at micromolar sulfate concentrations, (2) the consistent occurrence of δ18OSO4 minima at the chemocline that may be imparted during cryptic sulfur cycling, (3) that subsequent δ18OSO4 enrichments consistently preceded sulfide accumulation and δ34SSO4 enrichment in the suboxic zone of the water column, (4) that initial epilimnion Δ18OSO4-H2O values placed constraints on the maximum extent of δ18OSO4 evolution that occurred beneath the chemocline, (5) that observable changes in the metabolic composition of sulfur bacterial communities accompanied key inflections in the sulfur and oxygen isotope profiles of sulfate and sulfide within the water column, and (6) that, despite large overall differences in community structure, Δ34SSO4-H2S and Δ18OSO4-H2O values ultimately reached similar magnitudes in each lake.Item A Glacier through a Grain of Sand: Sediment Micromorphology from a Land-Terminating Glacier in West Greenland(2024-10) Woodie, Kayla Pearl; Licht, Kathy; Gilhooly, William P., III; Graly, JosephIsunnguata Sermia is a land terminating glacier in West Greenland with prominent upwellings of subglacial water in the outwash plain. Sediment that is suspended in the upwelling water is preserved in ice, creating a window into the subglacial environment. The presence of certain established microtextures, such as those caused by fluvial or high-stress processes, is indicative of a grain’s impact and transport history. Scanning electron microscopy (SEM) imaging of quartz sand grains is used to analyze this micromorphology. Across sand grains collected from different glacial depositional environments and the frozen subglacial water of Isunnguata Sermia, the microtexture distributions are extremely similar despite their different transport processes. While this may represent the limitations of microtexture analysis, it also suggests a high degree of sediment recycling in a basin that includes both the subglacial and the proglacial environment.Item Analysing Urban Air Pollution Using Low-Cost Methods and Community Science(2022-12) Heintzelman, Asrah; Filippelli, Gabriel; Moreno-Madriñan, Max J.; Wilson, Jeffrey S.; Wang, Lixin; Druschel, Gregory K.Rise in air pollution resulting in negative health externalities for humans has created an urgent need for cities and communities to monitor it regularly. At present we have insufficient ground passive and active monitoring networks in place which presents a huge challenge. Satellite imagery has been used extensively for such analysis, but its resolution and methodology present other challenges in estimating pollution burden. The objective of this study was to propose three low-cost methods to fill in the gaps that exist currently. First, EPA grade sensors were used in 11 cities across the U.S. to examine NO2. This is a simplistic way to assess the burden of air pollution in a region. However, this technique cannot be applied to fine scale analysis, which resulted in the next two components of this research study. Second, a citizen science network was established on the east side of Indianapolis, IN who hosted 32 Ogawa passive sensors to examine NO2 and O3 at a finer scale. These low-cost passive sensors, not requiring power, and very little maintenance, have historically tracked very closely with Federal Reference Monitors. Third, a low-cost PurpleAir PA-II-SD active sensors measuring PM2.5 were housed with the citizen scientists identified above. This data was uploaded via Wi-Fi and available via a crowd sourced site established by PurpleAir. These data sets were analyzed to examine the burden of air pollution. The second and third research studies enabled granular analyses utilizing citizen science, tree canopy data, and traffic data, thus accommodating some of the present limitations. Advancement in low-cost sensor technology, along with ease of use and maintenance, presents an opportunity for not just communities, but cities to take charge of some of these analyses to help them examine health equity impacts on their citizens because of air pollution.Item Analysis of Mercury Concentrations in Indiana Soil to Evaluate Patterns of Long-Term Atmospheric Mercury Deposition(2013-01-09) Crewe, Julie R.; Filippelli, Gabriel M.; Babbar-Sebens, Meghna; Risch, Martin R.Mercury (Hg) has proven to be a risk to the public, mainly through the consumption of fish. Because of this, many fish consumption advisories have been issued in Indiana. Although much is known about the global cycle of mercury, little is known about how local and regional emission sources of mercury impact local and regional mercury cycling. This study’s objective was to determine the scope of mercury concentration in central Indiana by using a broad grid of soil mercury measurements. Sampling was designed to capture the net retained mercury content in soils, and to determine whether spatial patterns in exist in soil mercury contents that could be related to emission sources of mercury and post-emission transport patterns from wind. Results from this study revealed significant differences in mercury concentrations for soils in central Indiana. The core of the study area, concentrated in the urban area of Indianapolis, exhibited soil mercury contents that were 20 times higher than values in the outskirts of the study area. The spatial pattern resembled a bulls-eye shape centered on Indianapolis, and with comparison to the reported Hg emission from local sources, including a coal-fired power plant, indicates a strong regional deposition signal linked to those emission sources but marked by wind-driven transport to the northeast. This effect of local emission sources resulting in local deposition indicates that limiting mercury emissions will have a net beneficial impact on local environmental quality and human health.Item Applications of geospatial analysis techniques for public health(2016-05-02) Stanforth, Austin Curran; Filippelli, Gabriel; Johnson, Daniel P.; Wang, Lixin; Wilson, Jeffrey; Moreno-Madriñán, Max J.; Jacinthe, Pierre-AndréGeospatial analysis is a generic term describing several technologies or methods of computational analysis using the Earth as a living laboratory. These methods can be implemented to assess risk and study preventative mitigation practices for Public Health. Through the incorporation Geographic Information Science and Remote Sensing tools, data collection can be conducted at a larger scale, more frequent, and less expensive that traditional in situ methods. These techniques can be extrapolated to be used to study a variety of topics. Application of these tools and techniques were demonstrated through Public Health research. Although it is understand resolution, or scale, of a research project can impact a study’s results; further research is needed to understand the extent of the result’s bias. Extreme heat vulnerability analysis was studied to validate previously identified socioeconomic and environmental variables influential for mitigation studies, and how the variability of resolution impacts the results of the methodology. Heat was also investigated for the implication of spatial and temporal resolution, or aggregation, influence on results. Methods studying the physical and socioeconomic environments of Dengue Fever outbreaks were also studied to identify patters of vector emergence.Item ASSESSING THE ROLE OF GEOLOGIC SETTING ON THE HYDROLOGY AND GROUND WATER GEOCHEMISTRY OF FENS IN THE GLACIATED MIDWESTERN UNITED STATES(2007-04-09T15:32:10Z) Graves, Dustin; Tedesco, Lenore P.; Vidon, Philippe G.; Jacinthe, Pierre-AndreABSTRACT Dustin Graves ASSESSING THE ROLE OF GEOLOGIC SETTING ON THE HYDROLOGY AND GROUND WATER GEOCHEMISTRY OF FENS IN THE GLACIATED MIDWESTERN UNITED STATES A water quality investigation of several fens located in the temperate glaciated Midwestern United States, near the southern limit of fen occurrence, was conducted to assess the role of geologic setting on the hydrogeochemical signature of fens and to compare hydrogeochemistry of fens located in different geographic and geologic settings. The five studied fens, located in the Central Till Plain physiographic region of Indiana, receive ground water sourced from glacial tills with very similar petrologic composition. These wetlands are hydrogeomorphically classified as slope wetlands with dominant ground water input. More specifically, these sites are inter-till / intra-till type fens (Type Ia and Ib) or outwash terrace type fens (Type II). Shallow ground water was collected just prior to surface interception (source water), and again after discharging into each fen (fen water) and measured for a suite of cations (Ca2+, Mg2+, K+, Na+) and anions (HCO3- SO42-, NO3-, NO2-, PO43-, and Cl-). Fen water hydroperiods showed similar dynamics, despite some variation in the hydrologic input of these systems (source water). Central Indiana fens are recognized as Ca2+, Mg2+, and HCO3- dominated systems. Fen water showed substantial evolution from source water at each study site, evidently the result of carbonate and gypsum dissolution dynamics. However, when only fen water is analyzed, results suggest that ground water of the southern fens represents geochemical similarity, with the exception of anthropogenic influence. The greatest geochemical variation among central Indiana fens can be attributed to Na+ and Cl-, which has been linked to road salt contamination at two of the study sites. This hydrogeochemical study also reveals that fens (slope wetlands) within this particular geologic setting of central Indiana show strong geochemical similarities to fens located throughout the temperate Northern Hemisphere. However, statistical analyses provide evidence that the parameters of Ca2+, HCO3-, and SO42- account for the greatest variation among these wetland communities, suggesting that calcium carbonate and gypsum dissolution dynamics are primarily fen specific while other parameters remain relatively homogenous across a wide geographical range. Lenore P. Tedesco, Ph. D.Item Attributes of Organic Phosphorus Exported from a Central Indiana Agricultural Watershed: Effects of Season and Hydrologic Flowpath(2023-05) Pitcock, Rebecca Jo; Jacinthe, Pierre-Andre; Filippelli, Gabriel; Wang, LixinThe export of phosphorus (P) from agricultural watersheds has been extensively investigated but monitoring efforts have generally focused on inorganic P (Pi or soluble reactive phosphorus [SRP]), the P fraction thought to be immediately available to algae. However, in settings where no-till management is implemented and organic matter accumulates on soil surface, the amount of organic P (Po) in agricultural drainage waters can be significant and may represent another important P source to fuel algal growth in receiving water bodies. From a 2018 monitoring study at a Central Indiana agricultural watershed, measured total P and SRP loss amounted to 1.22 and 0.17 kg P/ha/year, respectively, indicating that the bulk (84%) of P exported from that watershed was in organic form. Results also showed that tile drainage was the main pathway for P transport (96% of Po loss). In light of these observations, the bioavailability of Po in agricultural drainage waters was investigated in 2019, and the effect of hydrologic flow path (surface versus subsurface flow) on the biochemical attributes of Po was examined. In these assessments, the iron strip method and a suite of enzymatic assays were used to gain a better understanding of the chemical composition of the exported Po. Higher concentration of labile Po was consistently measured in tile discharge than in surface runoff (59% versus 38% of the total bioavailable P). Further, the concentration of EHP (enzymatically hydrolysable P), in the form of monoester, diester, and phytate compounds, was highest during the summer season, for both tile and surface pathways. This elevated bioavailability of Po during the summer is a concern because, in combination with favorable water temperature and solar radiation during that period, this could lead to enhanced Po mineralization and release of Pi, resulting in further algal proliferation and continued degradation of water quality. Considering the high prevalence of tile drainage in agricultural landscapes of the US Midwest, this finding underscores the need for further investigation of the impact of land management and climate on the speciation and bioavailability of Po in the region’s agricultural waters.Item Biological potential and diffusion limitation of methane oxidation in no-till soils(2014-05-21) Prajapati, Prajaya; Wang, Xianzhong; Martin, Pamela; Jacinthe, Pierre-AndréLong term no-till (NT) farming can improve the CH4 oxidation capacity of agricultural lands through creation of a favorable soil environment for methanotrophs and diffusive gas transport. However, limited data is available to evaluate the merit of that contention. Although the potential for biological CH4 oxidation may exist in NT soils, restricted diffusion could limit expression of that potential in fine-textured soils. A study was conducted to assess the CH4 oxidation potential and gaseous diffusivity of soils under plow till (PT) and NT for > 50 years. Intact cores and composite soils samples (0-10 and 10-20 cm) were collected from NT and PT plots located at a well-drained site (Wooster silt loam) and at a poorly-drained (Crosby silt loam) site in Ohio. Adjacent deciduous forest soils were also sampled to determine maximum rate expected in undisturbed soils in the region. Regardless of study sites and soil depth, CH4 oxidation rate (measured at near ambient CH4) and oxidation potential (Vmax, measured at elevated CH4) were 3-4 and 1.5 times higher in NT than in PT soils, respectively. Activity in the NT soils approached (66-80 %) that in the forest soils. Half saturation constants (Km) and threshold for CH4 oxidation (Th) were lower in NT (Km: 100.5 µL CH4 L-1; Th: 0.5 µL CH4 L-1) than in PT soils (Km: 134 µL CH4 L-1; Th: 2.8 µL CH4 L-1) suggesting a greater affinity of long-term NT soils for CH4, and a possible shift in methanotrophic community composition. CH4 oxidation rates were lower in intact soil cores compared to sieved soils, suggesting that CH4 oxidation was limited by diffusion, a factor that could lead to lower field-measured CH4 uptake than suggested by biological oxidation capacity measured in the laboratory. Regardless of soil drainage characteristic, long-term NT resulted in significantly higher (2-3 times) CH4 diffusivity (mean: 2.5 x 10-3 cm2 s-1) than PT (1.5 x 10-3 cm2 s-1), probably due to improved soil aggregation and greater macro-pores volume in NT soils. Overall, these results confirm the positive impact of NT on the restoration of the biological (Vmax, Km and Th) and physical (diffusivity) soil attributes essential for CH4 uptake in croplands. Long-term implementation of NT farming can therefore contribute to the mitigation of CH4 emission from agriculture.Item Breccia of Frog Lakes : reconstructing Triassic volcanism and subduction initiation in the east-central Sierra Nevada, California(2014-03-12) Roberts, Sarah Elizabeth; Barth, Andrew, 1958-; Rosenberg, Gary D.; Filippelli, Gabriel M.The Antler and Sonoma orogenies occurred along the southwest-trending passive Pacific margin of North America during the Paleozoic concluding with the accretion of the McCloud Arc. A southeast-trending sinistral transform fault truncated the continental margin in the Permian, becoming a locus for initiation of an east-dipping subduction zone creating the Sierran magmatic arc. Constrained in age between two early Triassic tuff layers, the volcanic clasts in the breccia of Frog Lakes represent one of the earliest records of mafic magmatism in the eastern Sierra Nevada. Tholeiitic rock clasts found in the breccia of Frog Lakes in the Saddlebag Lake pendant in the east central Sierra Nevada range in composition from 48% to 63% SiO2. Boninites produced by early volcanism of subduction initiation by spontaneous nucleation at the Izu-Bonin-Mariana arc are more depleted in trace element concentrations than the clasts while andesites from the northern volcanic zone of the Andes produced on crust 50 km thick have similar levels of enrichment and provide a better geochemical modern analogue. Textural analysis of the breccia of Frog Lakes suggest a subaqueous environment of deposition from a mature magmatic arc built on continental crust > 50 km thick during the Triassic. The monzodiorites of Saddlebag and Odell Lakes are temporal intrusive equivalents of the breccia of Frog Lakes and zircon geochemistry indicates a magmatic arc petrogenesis.