Metal-free visible-light-promoted C(sp3)-H functionalization of aliphatic cyclic ethers using trace O2

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dc.contributor.authorNiu, Ben
dc.contributor.authorBlackburn, Bryan G.
dc.contributor.authorSachidanandan, Krishnakumar
dc.contributor.authorCooke, Maria Victoria
dc.contributor.authorLaulhé, Sébastien
dc.contributor.departmentChemistry and Chemical Biology, School of Science
dc.date.accessioned2024-01-04T10:03:05Z
dc.date.available2024-01-04T10:03:05Z
dc.date.issued2021
dc.description.abstractPresented is a light-promoted C-C bond forming reaction yielding sulfone and phosphate derivatives at room temperature in the absence of metals or photoredox catalyst. This transformation proceeds in neat conditions through an auto-oxidation mechanism which is maintained through the leaching of trace amounts of O2 as sole green oxidant.
dc.eprint.versionAuthor's manuscript
dc.identifier.citationNiu B, Blackburn BG, Sachidanandan K, Cooke MV, Laulhé S. Metal-free visible-light-promoted C(sp3)-H functionalization of aliphatic cyclic ethers using trace O2. Green Chem. 2021;23(23):9454-9459. doi:10.1039/d1gc03482k
dc.identifier.urihttps://hdl.handle.net/1805/37593
dc.language.isoen_US
dc.publisherRoyal Society of Chemistry
dc.relation.isversionof10.1039/d1gc03482k
dc.relation.journalGreen Chemistry
dc.rightsPublisher Policy
dc.sourcePMC
dc.subjectC-C bond
dc.subjectSulfone
dc.subjectPhosphate derivatives
dc.titleMetal-free visible-light-promoted C(sp3)-H functionalization of aliphatic cyclic ethers using trace O2
dc.typeArticle
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