Metal-free visible-light-promoted C(sp3)-H functionalization of aliphatic cyclic ethers using trace O2
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Date
2021
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American English
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Royal Society of Chemistry
Abstract
Presented is a light-promoted C-C bond forming reaction yielding sulfone and phosphate derivatives at room temperature in the absence of metals or photoredox catalyst. This transformation proceeds in neat conditions through an auto-oxidation mechanism which is maintained through the leaching of trace amounts of O2 as sole green oxidant.
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Niu B, Blackburn BG, Sachidanandan K, Cooke MV, Laulhé S. Metal-free visible-light-promoted C(sp3)-H functionalization of aliphatic cyclic ethers using trace O2. Green Chem. 2021;23(23):9454-9459. doi:10.1039/d1gc03482k
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Green Chemistry
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PMC
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Article
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