Palladium-Catalyzed Decarboxylative Alkoxycarbonylation of Potassium Aryltrifluoroborates with Potassium Oxalate Monoesters

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dc.contributor.authorMiao, Jinmin
dc.contributor.authorFang, Ping
dc.contributor.authorJagdeep, Sahota
dc.contributor.authorGe, Haibo
dc.contributor.departmentDepartment of Chemistry and Chemical Biology, School of Scienceen_US
dc.date.accessioned2017-09-28T19:22:12Z
dc.date.available2017-09-28T19:22:12Z
dc.date.issued2016-02
dc.description.abstractPalladium-catalyzed decarboxylative alkoxycarbonylation of potassium aryltrifluoroborates with potassium oxalate monoesters in the presence of potassium persulfate was performed under mild conditions. A number of benzoyl esters with a wide variety of substituents at different positions were efficiently synthesized with this method. Mechanism of the palladium-catalyzed decarboxylative carbonylation of aryltrifluoroborates was studied, and a radical-mediated Pd(II)/Pd(IV) catalytic cycle was proposed.en_US
dc.eprint.versionAuthor's manuscripten_US
dc.identifier.citationMiao, J., Fang, P., Jagdeep, S., & Ge, H. (2016). Palladium-catalyzed decarboxylative alkoxycarbonylation of potassium aryltrifluoroborates with potassium oxalate monoesters. Organic Chemistry Frontiers, 3(2), 243–250. https://doi.org/10.1039/C5QO00349Ken_US
dc.identifier.urihttps://hdl.handle.net/1805/14203
dc.language.isoenen_US
dc.publisherRSCen_US
dc.relation.isversionof10.1039/C5QO00349Ken_US
dc.relation.journalOrganic Chemistry Frontiersen_US
dc.rightsPublisher Policyen_US
dc.sourceAuthoren_US
dc.subjectpalladium-catalyzed decarboxylative alkoxycarbonylationen_US
dc.subjectpotassium aryltrifluoroboratesen_US
dc.subjectpotassium oxalate monoestersen_US
dc.titlePalladium-Catalyzed Decarboxylative Alkoxycarbonylation of Potassium Aryltrifluoroborates with Potassium Oxalate Monoestersen_US
dc.typeArticleen_US
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