Evidence of dynamical effects and critical field in a cobalt spin crossover complex
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2022-01
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American English
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Royal Society of Chemistry
Abstract
The [Co(SQ)2(4-CN-py)2] complex exhibits dynamical effects over a wide range of temperature. The orbital moment, determined by X-ray magnetic circular dichroism (XMCD) with decreasing applied magnetic field, indicates a nonzero critical field for net alignment of magnetic moments, an effect not seen with the spin moment of [Co(SQ)2(4-CN-py)2].
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Ekanayaka, T. K., Wang, P., Yazdani, S., Phillips, J. P., Mishra, E., Dale, A. S., N’Diaye, A. T., Klewe, C., Shafer, P., Freeland, J., Streubel, R., Wampler, J. P., Zapf, V., Cheng, R., Shatruk, M., & Dowben, P. A. (2022). Evidence of dynamical effects and critical field in a cobalt spin crossover complex. Chemical Communications (Cambridge, England), 58(5), 661–664. https://doi.org/10.1039/d1cc05309d
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1359-7345, 1364-548X
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Chemical Communications
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