Spatial and temporal variations of tap water 17O-excess in China

Abstract

Compared to tap water δ2H and δ18O, tap water 17O-excess preserves additional information about source water dynamics. In this study, we provide the first report of 17O-excess variations of tap water across China (652 samples). Annual 17O-excess of tap waters at the national scale did not show obvious spatial pattern, and was almost unaffected by local environmental factors except in the Qinghai-Tibet Plateau region with a strong latitudinal trend. The mean 17O-excess values in different seasons were not significantly different. The isotopic compositions of most of the tap waters at the annual and seasonal scale were likely influenced by the equilibrium fractionation effect (δ′18O-δ′17O slope ranged from 0.5277 to 0.5301), except for the northwest region in the summer (slope = 0.5264) influenced by kinetic fractionation associated with re-evaporation effect. Based on the information of tap water source distribution, site aridity index and the known precipitation δ18O values, a subset of the tap water can be considered as precipitation proxy. Different from the obvious spatial characteristics of precipitation δ18O, precipitation 17O-excess did not show a clear spatial pattern. But it revealed much detailed precipitation formation mechanisms related to different climate regions and geographical conditions. The lower 17O-excess values of the precipitation-sourced tap waters were caused by kinetic fractionation associated with supersaturation process in snow or glacier formation and re-evaporation effect in some arid regions. The higher 17O-excess values of the precipitation-sourced tap waters in the inland were caused by continental moisture recycling, while likely caused by multiple factors in the southeast coastal region including short transport from ocean source and the humid local environment. Overall, this study provides a unique tap water 17O-excess dataset across China, and probes the precipitation formation mechanisms using tap waters.