Browsing by Subject "transition metal-promoted α-C–H bond functionalization"

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    Silver-Promoted Site-Selective Intramolecular Cyclization of 2-Methylthiobenzamide Through α-C(sp3)–H Functionalization
    (ACS, 2019-11) Yang, Ke; Niu, Ben; Ma, Zhiyan; Wang, Hui; Lawrence, Brianna; Ge, Haibo; Chemistry and Chemical Biology, School of Science
    Silver-mediated intramolecular α-C(sp3)–H bond functionalization of the methylthio group has been established in the presence of Selectfluor as an additive. This novel strategy provides efficient access to various diverse sulfur-based heterocycles with good yields and functional group compatibility. It is noteworthy that the completely novel benzooxathiin-4-imine skeletons were reported for the first time in this study.