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Item Six-electron organic redoxmers for aqueous redox flow batteries(Royal Society of Chemistry, 2022-12) Fang, Xiaoting; Cavazos, Andres T.; Li, Zhiguang; Li, Chenzhao; Xie, Jian; Wassall, Stephen R.; Zhang, Lu; Wei, Xiaoliang; Physics, School of ScienceWe have developed a novel molecular design that enables six-electron redox activity in fused phenazine-based organic scaffolds. Combined electrochemical and spectroscopic tests successfully confirm the two-step 6e− redox mechanism. This work offers an opportunity for achieving energy-dense redox flow batteries, on condition that the solubility and stability issues are addressed.