Browsing by Subject "potassium aryltrifluoroborates"

Now showing 1 - 1 of 1
  • Thumbnail Image
    Item
    Palladium-Catalyzed Decarboxylative Alkoxycarbonylation of Potassium Aryltrifluoroborates with Potassium Oxalate Monoesters
    (RSC, 2016-02) Miao, Jinmin; Fang, Ping; Jagdeep, Sahota; Ge, Haibo; Department of Chemistry and Chemical Biology, School of Science
    Palladium-catalyzed decarboxylative alkoxycarbonylation of potassium aryltrifluoroborates with potassium oxalate monoesters in the presence of potassium persulfate was performed under mild conditions. A number of benzoyl esters with a wide variety of substituents at different positions were efficiently synthesized with this method. Mechanism of the palladium-catalyzed decarboxylative carbonylation of aryltrifluoroborates was studied, and a radical-mediated Pd(II)/Pd(IV) catalytic cycle was proposed.