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Item PALEOPRODUCTIVITY VARIATIONS IN THE EASTERN CENTRAL EQUATORIAL PACIFIC OCEAN ON GLACIAL TIMESCALES(2008-08-22T14:19:57Z) Hale, Sarah Beth; Filippelli, Gabriel M.; Licht, Kathy J.; Swope, R. JefferyPaleoproductivity records during the late Pleistocene are sparse. The equatorial Pacific and the Southern Ocean are collectively responsible for the majority of the new production in the oceans. The nutrient and carbon mass balances of these regions must be constrained in order to fully understand net global biological productivity on glacial timescales. The geochemistry of two east-central equatorial Pacific Ocean cores (02° 33.48 N; 117° 55.06 W) and (00° 15.42 S; 113° 00.57 W) are used to examine changes in biological productivity due to nutrient upwelling on glacial timescales during the Pleistocene. The cores were recovered in March 2006 on the AMAT03 cruise, a site survey cruise for IODP Proposal 626. The total concentrations of Ca, Ti, Fe, Al, P, Ba, S, Mg, Sr, Zn and Mn were determined by a total sediment digestion followed by analysis by inductively coupled plasma-atomic emission spectrometry (ICP). Original solid forms of P for 34 evenly spaced samples throughout one core were determined using the P Sequential Extraction technique. This study is attempting to compare upwelling and productivity records by determining temporal records of nutrient proxies, using Latimer and Filippelli (2006) which focused on the Southern Ocean. Equatorial upwelling and Southern Ocean upwelling both appear to exhibit strong glacial timescale variability. The P geochemistry results indicate that the P signal is largely biological. The equatorial Pacific evidence, in accordance with Southern Ocean patterns, supports a nutrient budget-driven productivity signal over time. Gabriel M. Filippelli, Ph. D, Committee ChairItem The “White Ocean” Hypothesis: A Late Pleistocene Southern Ocean Governed by Coccolithophores and Driven by Phosphorus(Frontiers Media, 2012-07-02) Flores, José-Abel; Filippelli, Gabriel M.; Sierro, Francisco J.; Latimer, Jennifer; Earth and Environmental Sciences, School of SciencePaleoproductivity is a critical component in past ocean biogeochemistry, but accurate reconstructions of productivity are often hindered by limited integration of proxies. Here, we integrate geochemical (phosphorus) and micropaleontological proxies at millennial timescales, revealing that the coccolithophore record in the Subantarctic zone of the South Atlantic Ocean is driven largely by variations in marine phosphorus availability. A quantitative micropaleontological and geochemical analysis carried out in sediments retrieved from Ocean Drilling Program Site 1089 (Subantarctic Zone) reveals that most of the export productivity in this region over the last 0.5 my was due to coccolithophores. Glacial periods were generally intervals of high productivity, with productivity reaching a peak at terminations. Particularly high productivity was observed at Termination V and Termination IV, events that are characterized by high abundance of coccolithophores and maxima in the phosphorus/titanium and strontium/titanium records. We link the increase in productivity both to regional oceanographic phenomena, i.e., the northward displacement of the upwelling cell of the Antarctic divergence when the ice-sheet expanded, and to the increase in the inventory of phosphorus in the ocean due to enhanced transfer of this nutrient from continental margins during glacial lowstands in sea level. The Mid-Brunhes interval stands out from the rest of the record, being dominated by the small and highly calcified species Gephyrocapsa caribbeanica that provides most of the carbonate in these sediments. This likely represents higher availability of phosphorus in the surface ocean, especially in mesotrophic and oligotrophic zones. Under these condition, some coccolithophore species developed an r-strategy (opportunistic species; growth rate maximized) resulting in the bloom of G. caribbeanica. These seasonal blooms of may have induced “white tides” similar to those observed today in Emiliania huxleyi.