Browsing by Subject "Ceramics"
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Item 2D transition metal carbides (MXenes) in metal and ceramic matrix composites(Springer, 2021-06-02) Wyatt, Brian C.; Nemani, Srinivasa Kartik; Anasori, Babak; Mechanical and Energy Engineering, School of Engineering and TechnologyTwo-dimensional transition metal carbides, nitrides, and carbonitrides (known as MXenes) have evolved as competitive materials and fillers for developing composites and hybrids for applications ranging from catalysis, energy storage, selective ion filtration, electromagnetic wave attenuation, and electronic/piezoelectric behavior. MXenes’ incorporation into metal matrix and ceramic matrix composites is a growing field with significant potential due to their impressive mechanical, electrical, and chemical behavior. With about 50 synthesized MXene compositions, the degree of control over their composition and structure paired with their high-temperature stability is unique in the field of 2D materials. As a result, MXenes offer a new avenue for application driven design of functional and structural composites with tailorable mechanical, electrical, and thermochemical properties. In this article, we review recent developments for use of MXenes in metal and ceramic composites and provide an outlook for future research in this field.Item Arsenal(2018) Carroll, Brenna; Jefferson, Corey; Baker, Lesley; Robertson, JeanTraumatic experience inspires the human drive for expression. Survivors carry the memory of trauma with them throughout their lives while they struggle to comprehend its impact. They maintain a fragile stability as their capacity to more forward is challenged and their perception of the world around them is altered. The force of memory compels those who have survived a traumatic event to build a defensive arsenal and to search for and to convey an understanding of their experience. My minimalist abstract ceramic sculpture examines the incidence of trauma and explores the transference of concepts and emotions associated with its effects.Item askew(2014-05) Wichmann, Stephanie; Jefferson, CoreyEvery moment is everywhere . Being human is a mass of feelings and the felt. One can never be certain who they are moment to moment for the body is always changing and adjusting, along side partners’, time and space. Nothing is constant.Item Ceragami(2016) Patel, Mona; Jefferson, Corey; Baker, Lesley; Giddings, AnitaCeramics is one of the oldest mediums of creating works of art over the past centuries; however there has been a significant improvement and advancements towards creating different forms with it. I intend to capture the outcomes of the interdependent qualities of these materials. As the work is a combination of ceramics and Origami, I originated the term 'Ceragami'.Item Effect of lithium disilicate ceramic thickness, shade and translucency on transmitted irradiance and knoop microhardness of a light cured luting resin cement(Springer, 2021-07-31) Borges, Lincoln Pires Silva; Borges, Gilberto Antônio; Correr, Américo Bortolazzo; Platt, Jeffrey A.; Kina, Sidney; Correr-Sobrinho, Lourenço; Costa, Ana Rosa; Biomedical and Applied Sciences, School of DentistryThis in vitro study evaluates the influence of pressed lithium disilicate thickness, shade and translucency on the transmitted irradiance and the Knoop microhardness (KHN) of a light-cured resin cement at two depths. One hundred and thirty-five ceramic discs of IPS e.max Press (Ivoclar Vivadent) were fabricated and divided into twenty-seven groups (n = 5) according to the association between translucency: HT (hight translucency), LT (low translucency), and MO (medium opacity); shade: BL2, A1 and A3.5; and thickness: 0.5 mm, 1.5 mm, and 2.0 mm. One side of each ceramic disc was finished, polished and glazed. The irradiance (mW/cm²) of a multiwave LED light curing unit (Valo, Ultradent) was evaluated with a potentiometer (Ophir 10ª-V2-SH, Ophir Optronics) without (control group) or with interposition of ceramic samples. The microhardness of Variolink Esthetic LC resin cement (Ivoclar Vivadent) was evaluated after 24 h at two depths (100 μm and 700 μm). Data were submitted to ANOVA followed by Tukey's test (α = 0.05). Irradiance and KHN were significantly influenced by ceramic thickness (p < 0.0001), shade (p < 0.001), translucency (p < 0.0001) and depth (p < 0.0001). Conclusions: the interposition of increasing ceramic thicknesses significantly reduced the irradiance and microhardness of resin cement. Increased depth in the resin cement showed significantly reduced microhardness for all studied groups. Increased ceramic opacity reduced the KHN of the resin cement at both depths for all ceramic thicknesses and shades.Item Effect of Toothbrushing on a Monolithic Dental Zirconia Submitted to an Accelerated Hydrothermal Aging(2022) Almajed, Norah; Sochacki, Sabrina Feitosa; Cook, Norman Blaine; Capin, Oriana ReisObjectives: The objectives of this study were (1) to evaluate the biaxial flexural strength of monolithic 3Y-TZP ceramic specimens and (2) to assess their surface roughness after being submitted to accelerated hydrothermal aging (simulation 1-10 years of aging); and simulated toothbrushing (simulation 1-10 years of toothbrushing). Materials/Methods: 84 discs of monolithic zirconia (Lava Plus High Translucency Zirconia, 3M ESPE) were prepared, sintered (1450°C, 2h), and randomly allocated into four experimental groups as follows: Control group (CT): no HA and no toothbrushing; 1-year group (1YR): 20 minutes of HA and 10,000 cycles of toothbrushing; 5 years group (5 YR): 100 minutes of HA and 50,000 cycles of toothbrushing; and 10 years group (10 YR): 200 minutes of HA and 100,000 cycles of toothbrushing. Specimens were submitted to autoclave hydrothermal aging at 134°C and 2.0 bar, followed by toothbrush simulation. After aging, specimens in each group were submitted to the biaxial flexural strength test (ISO 6872) using a universal testing machine, and the number of fragments was evaluated. Surface roughness was performed before and after aging using a noncontact profilometer (Ra, Rq, and Rz parameters). For the statistics, one-way analysis of variance (ANOVA) and pairwise comparison were used (α=0.05). Hypothesis: The accelerated hydrothermal aging and simulated toothbrushing will affect the results of the biaxial flexural strength and surface roughness of the zirconia specimens. Results: No significant aging effects were detected for the biaxial flexural strength (p=0.239) for groups CT (874.25±124.61 MPa), 1YR (869.56±132.60 MPa), 5YR (854.40±122.34 MPa), and 10YR (948.55±144.85 MPa). In addition, no significant aging effects were detected comparing the number of fragments, with a minimum of two and a maximum of five fragments (p=0.325). The collected data on the changes in surface roughness after hydrothermal aging and toothbrush simulation showed that for the parameters Ra and Rq, group 1YR presented significantly higher surface roughness than groups 5YR and 10YR. For the parameter Rz, group 1YR presented significantly higher surface roughness than groups 5YR and 10YR. In addition, group 5YR showed higher surface roughness than group 10YR. Conclusion: Hydrothermal aging associated with simulated toothbrushing did not significantly impact the biaxial flexural strength of monolithic 3Y-TZP zirconia. However, there was a significant initial increase in the zirconia surface roughness, which decreased after simulating five and ten years of aging.Item Effectiveness of universal adhesive bonding agents on the shear bond strength to lithium disilicate ceramics(2015) AlRabiah, Mohammed A.; Platt, Jeffery A.; Levon, John A.; Brown, David T.; Chu, Tien-Min Gabriel; Bottino, Marco C.Background: All-ceramic restorations have excellent esthetic outcomes compared with other restorative materials. Lithium disilicate is classified as one of many silica-based all-ceramic materials. Currently, companies have provided single-step adhesives, known as universal adhesives, compatible with different restorative materials including lithium disilicate. Many studies have reported greater bond strengths when using a silane to treat the lithium disilicate before applying the bonding agent. Moreover, few studies were published comparing the bond strength when using the universal adhesive alone. Purpose: The objective of this study was to evaluate and compare shear bond strength of three universal adhesives to lithium disilicate ceramic restorative material. Materials and Methods: Three universal adhesive bonding agents were selected from commercially available adhesives. 408 IPS e.max CAD ceramic discs were processed, fired, and etched for 20s. The specimens were divided into six groups. The first three groups used the universal adhesive directly. The remaining three groups were treated with silane. Then, a composite resin cylinder was placed on top of the adhesive using a bonding jig. Each group was subdivided into four equal subgroups (n = 17), subjected to different aging simulation procedures: 24 h, one month with 5000 thermocycles, two months with 5000 cycles, and three months with 5000 cycles. Then, specimens were debonded using shear force by a universal testing machine (MTS). Results: Shear bond strength was greater with silane than without silane (p < 0.0001), regardless of the levels of adhesive or time. Shear bond strength was significantly greater at 24h and 1m than at 2m (p < 0.0001) or 3m (p < 0.0001) regardless of the adhesive or the presence of silane. Debonded specimens were examined under a stereomicroscope at X45 magnification to evaluate the fracture pattern. SEM was used to prove the results were considered as mixed failure. Conclusion: The optimal bonds to lithium disilicate are achieved by application of silane prior to application of a universal adhesive. Although the constituent silane in the universal adhesive was not effective in optimizing the resin to ceramic bond, silane should always be applied to lithium disilicate prior to bonding.Item Effects of etching duration on the surface roughness, surface loss, flexural strength, and shear bond strength to a resin cement of e.max cad glass ceramic(2017) Al-Johani, Hanan; Chu, Tien-Min Gabriel; Platt, Jeffrey A.; Cook, Norman B.; Bottino, Marco C.Background: Long-term retention of ceramic restorations is dependent on the bond strength of the luting resin to both the tooth and porcelain substrates. In order to achieve successful bonding, the surface of the porcelain substrate must be modified to increase the surface roughness, and this can be achieved chemically by hydrofluoric (HF) acid etching. However, prolonged HF acid etching has shown to have a weakening effect on the evaluated lithium disilicate glass-ceramics. Therefore, it is essential to quantify the required etching duration of HF acid to minimize the possible deleterious effects on ceramic strength while maximizing the bond strength to tooth structure. Objectives: To evaluate the effects of HF acid etching duration on the surface roughness, surface loss, flexural strength, and shear bond strength of IPS e.max CAD (Ivoclar Vivadent) lithium disilicate-based glass ceramic to a resin cement. Hypothesis: The differences in HF acid etching durations will not have a significant effect on the surface roughness, surface loss, flexural strength, or shear bond strength of IPS e.max CAD to a resin cement. Methods: 168 specimens were prepared from IPS e.max CAD blocks. All specimens were polished and sonically cleaned in distilled water. Specimens were fired in the vacuum pump furnace according to the manufacturer’s instructions. Specimens were then divided into 4 groups, according to etching durations, then further divided into 3 subgroups, according to the properties tested. Group A was not etched (control), Groups B, C and D were etched with 5-percent HF acid (IPS Ceramic Etching gel, Ivoclar Vivadent) for 20 s, 60 s and 90 s respectively. The morphologies of both etched and non-etched surfaces in specimens of subgroup 1 of each etching group (n = 16/group) were observed under scanning electron microscopy (SEM). In addition, non-contact surface profilometry (Proscan 2000) was used to calculate the surface loss and to examine the surface roughness of the etched ceramic surfaces and roughness values (Ra, Rq) were documented for each group. Furthermore, etched specimens of subgroup 2 (n = 16/group) were silanated (Monobond Plus, Ivoclar Vivadent) and cemented with a resin cement (Multilink Automix, Ivoclar Vivadent). The shear bond strength (SBS) was measured using a universal mechanical testing machine. For each etching group, subgroup 3 specimens (n = 10/group) were loaded to failure in a three-point bending test to measure their flexural strength values using a universal mechanical testing machine. Data for surface roughness, surface loss, and flexural strength were analyzed using one-way analysis of variance (ANOVA), to identify the significant effects of different HF acid etching durations. Data for shear bond strength test were analyzed using two-way ANOVA to test the effects of etching duration, storage for 24 hours/thermocycling, and their interaction. All pair-wise comparisons from ANOVA analysis were made using Fisher’s Protected Least Significant Differences to control the overall significance level at 5 percent. Results: Difference in HF etching durations did not have a significant effect on surface roughness values Ra or Rq (p = 0.3408; p = 0.3245) respectively, but had a significant effect on surface loss (p = 0.0006). SBS values were not significantly different between experimental groups (p = 0.4650); however, SBS values after 24-h storage were significantly higher than that found after thermocycling (p = 0.0166) among different etching durations. Finally, different HF etching durations did not have a significant effect on flexural strength values (p = 0.1260). Conclusion: Within the limitations of this study, different HF etching durations did not have a significant effect on surface roughness, flexural strength, or shear bond strength of IPS e.max CAD. However, the different etching durations significantly affected the surface loss of the lithium disilicate glass ceramics.Item Extrinsic Characterization Sustainability in Zirconia Reinforced Lithium Silicate Ceramics(2021-04-08) Gadah, Thrya; May, Jaren; Levon, John; Chu, Tien-Min G; Gregory, Richard; Wei Shao, Lin; Feitosa, SabrinaABSTRACT OBJECTIVE. To investigate the effect of aging on the surface roughness and the color sustainability of externally characterized zirconia reinforced lithium silicate glass-ceramics treated with different surface protocols. METHODS. Sixty blocks (12-mm X 14-mm; 1.5-mm) of pre-crystalized zirconia reinforced-lithium silicate glass-ceramic (Vita Suprinity, Vita Zahnfabrick, Germany) CAD/CAM were crystalized and treated with different surface protocols, as extrinsic characterization (EC), mechanical polishing (MP), glaze layer (GL), surface adjustment (SA) and no treatment – control group (CG). Experimental groups (n=10) were divided as follow: CG; EC-MP-GZ; EC-GZ; EC-MP; EC-GZ-SA-GZ; EC-GZ-SA-MP and submitted to thermocycling (5,000 cycles, 5-55C) and toothbrushing simulation (5,000 cycles). Surface roughness (Ra and Rq), color change (CIED2000) and biofilm growth were evaluated. Statistical analysis was performed with a two-sided 5% significance level for all tests. RESULTS. For the parameter RaX, the control differed from EC-GZ and EC-MP (p = 0.04). For the parameter RqX, EC-GZ presented higher surface roughness compared than EC-MP-GZ and the group EC-GZ-SA-MP (p=0.02). EC-MP (p<0.01) and the EC-GZ-SA-MP (p<0.01) showed higher color change E00 after aging, while CG and EC-MP-GZ the least. For the biofilm growth, no significant group effect on bacteria counts was found (p=0.089). CONCLUSION. The aging protocol affected the surface roughness, and color of externally characterized zirconia reinforced lithium silicate glass-ceramics submitted to different surface treatment protocols. In the present study, when the mechanical polishing was performed before glaze application, the slightest color change and surface roughness were observed compared to the other surface treatments. Bacteria were not able to grow in the material surface, under the conditions tested in the present study.Item Extrusion Based Ceramic 3D Printing - Printer Development, Part Characterization, and Model-Based Systems Engineering Analysis(2020-12) Pai Raikar, Piyush Shrihari; Zhang, Jing; Agarwal, Mangilal; Anasori, BabakCeramics have been extensively used in aerospace, automotive, medical, and energy industries due to their unique combination of mechanical, thermal, and chemical properties. The objective of this thesis is to develop an extrusion based ceramic 3D printing process to digitally produce a casting mold. To achieve the objective, an in-house designed ceramic 3D printer was developed by converting a filament based plastic 3D printer. For mold making applications, zircon was selected because it is an ultra-high temperature ceramic with high toughness and good refractory properties. Additionally, alumina, bioglass, and zirconia slurries were formulated and used as the feedstock material for the ceramic 3D printer. The developed 3D printing system was used to demonstrate successful printing of special feature parts such as thin-walled high aspect ratio structures and biomimetically inspired complex structures. Also, proof of concept with regard to the application of 3D printing for producing zircon molds and casting of metal parts was also successfully demonstrated. To characterize the printed parts, microhardness test, scanning electron microscopy (SEM), and X-ray diffraction (XRD) analyses were conducted. The zircon samples showed an increase in hardness value with an initial increase in heat treatment temperature followed by a drop due to the development of porosity in the microstructure, caused by the decomposition of the binder. The peak hardness value for zircon was observed to be 101±10 HV0.2. Similarly, the microhardness values of the other 3D printed ceramic specimens were observed to increase from 37±3 to 112±5 HV0.2 for alumina, 23±5 to 35±1 HV0.2 for bioglass, and 22±5 to 31±3 HV0.2 for zirconia, before and after the heat-treatment process, respectively. Finally, a system model for the ceramic 3D printing system was developed through the application of the model-based systems engineering (MBSE) approach using the MagicGrid framework. Through the system engineering effort, a logical level solution architecture was modeled, which captured the different system requirements, the system behaviors, and the system functionalities. Also, a traceability matrix for the system from a very abstract logical level to the definition of physical requirements for the subsystems was demonstrated.