Browsing by Subject "Batteries"

Now showing 1 - 5 of 5
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    2D metal carbides and nitrides (MXenes) for energy storage
    (Nature Publishing Group, 2017-01-17) Anasori, Babak; Lukatskaya, Maria R.; Gogotsi, Yury; Mechanical Engineering and Energy, School of Engineering and Technology
    The family of 2D transition metal carbides, carbonitrides and nitrides (collectively referred to as MXenes) has expanded rapidly since the discovery of Ti3C2 in 2011. The materials reported so far always have surface terminations, such as hydroxyl, oxygen or fluorine, which impart hydrophilicity to their surfaces. About 20 different MXenes have been synthesized, and the structures and properties of dozens more have been theoretically predicted. The availability of solid solutions, the control of surface terminations and a recent discovery of multi-transition-metal layered MXenes offer the potential for synthesis of many new structures. The versatile chemistry of MXenes allows the tuning of properties for applications including energy storage, electromagnetic interference shielding, reinforcement for composites, water purification, gas- and biosensors, lubrication, and photo-, electro- and chemical catalysis. Attractive electronic, optical, plasmonic and thermoelectric properties have also been shown. In this Review, we present the synthesis, structure and properties of MXenes, as well as their energy storage and related applications, and an outlook for future research.
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    Context-Aware Collaborative Intelligence With Spatio-Temporal In-Sensor-Analytics for Efficient Communication in a Large-Area IoT Testbed
    (IEEE, 2021) Chatterjee, Baibhab; Seo, Dong-Hyun; Chakraborty, Shramana; Avlani, Shitij; Jiang, Xiaofan; Zhang, Heng; Abdallah, Mustafa; Raghunathan, Nithin; Mousoulis, Charilaos; Shakouri, Ali; Bagchi, Saurabh; Peroulis, Dimitrios; Sen, Shreyas; Electrical and Computer Engineering, Purdue School of Engineering and Technology
    Decades of continuous scaling has reduced the energy of unit computing to virtually zero, while energy-efficient communication has remained the primary bottleneck in achieving fully energy-autonomous Internet-of-Things (IoT) nodes. This article presents and analyzes the tradeoffs between the energies required for communication and computation in a wireless sensor network, deployed in a mesh architecture over a 2400-acre university campus, and is targeted toward multisensor measurement of temperature, humidity and water nitrate concentration for smart agriculture. Several scenarios involving in-sensor analytics (ISA), collaborative intelligence (CI), and context-aware switching (CAS) of the cluster head during CI has been considered. A real-time co-optimization algorithm has been developed for minimizing the energy consumption in the network, hence maximizing the overall battery lifetime. Measurement results show that the proposed ISA consumes ≈ 467× lower energy as compared to traditional Bluetooth low energy (BLE) communication, and ≈ 69500× lower energy as compared with long-range (LoRa) communication. When the ISA is implemented in conjunction with LoRa, the lifetime of the node increases from a mere 4.3 h to 66.6 days with a 230-mAh coin cell battery, while preserving >99% of the total information. The CI and CAS algorithms help in extending the worst case node lifetime by an additional 50%, thereby exhibiting an overall network lifetime of ≈ 104 days, which is >90% of the theoretical limits as posed by the leakage current present in the system, while effectively transferring information sampled every second. A Web-based monitoring system was developed to continuously archive the measured data, and for reporting real-time anomalies.
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    Design, Optimization and Study on Multiple Electrochemical Systems in Energy Dense Rechargeable Lithium Batteries
    (2019-08) Cui, Yi; Zhu, Likun; Pan, Liang; Mukherjee, Partha P.; Schubert, Peter J.
    Lithium-ion batteries (LIBs) are commonly and widely applied in current numerous devices such as smart phones, laptops, electric vehicles and medical devices. The LIBs are considered as a mature technology in todays commercial market bene ted from their uncomplicated lithium intercalation and de-intercalation reactions, stable cycling performance and good working life as energy storage devices and power resources. However, the conventional LIBs with technical limits such as high weight, low lithium utilization and low speci c energy density hit the bottlenecks of further improvements and optimizations for meeting the growing power supply requirements. It is urgent to develop the second generations of rechargeable lithium batteries, which have the bene ts of low cost, high speci c capacity and high energy density with light weight. In this context, lithium-sulfur batteries (LSBs) and lithium-selenium (Li-Se) batteries attract much attention due to the high possibility to meet the requirements of high speci c capacity and high energy density. However, the technical challenges they are facing put some barriers before they can be successfully commercialized. By a brief summary, the challenges to be solved are current low energy density because of requiring large amount of liquid electrolyte, the highly ammability and unsafety of lithium metal, low active material content due to the necessary requirement of carbon and binder, and severe so-called shuttle effect resulting in low Coulombic effciency. Before solving these challenges, Li-S batteries or Li-Se batteries are unlikely to be successfully commercialized in our market. Therefore, numerous research is aimed at solving the challenges and further developing more advanced Li-S and Li-Se battery systems. In the present dissertation, the contributions are mainly focused on sulfur-based and selenium-based materials, which aim to solve the current existing challenges and improve the battery performance, herein obtain a higher potential for application. Four chapters are included in this dissertation, which aim to present the four studied projects. The rst research conducted in this dissertation is developing organo S/Se hybrid materials which require low E/S ratios of liquid electrolyte and show light shuttle effect, therefore indicate promising high energy density and cycling life. Secondly, the tin foil is used as lithium sources instead of metallic lithium anode, then incorporated with sulfur cathode as a full cell. The full cell design provides the potential using a metallic anode other than pure lithium and increase the safety factor of a battery system. In addition, nano-scale selenium/carbon nanotubes composite electrode is synthesized via a chemical reduction method. With the optimization on thickness of the composite electrodes, the Se cathode has an active material content of ~60% and shows stable long cycling life with maximizing the utilization of selenium. The nal research conducted in this dissertation is applying a macro molecule named cyanostar, which has the ability to chemically bind with polysul de species, thereupon to alleviate the shuttle effect in Li-S batteries. With the evidence from chemistry analysis and electrochemical comparison results presented in this dissertation, cyanostar is proven to have the potential for further applications in Li-S batteries.
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    Poly(vinylidene fluoride-hexafluoropropylene) polymer electrolyte for paper-based and flexible battery applications
    (AIP, 2016-06-01) Aliahmad, Nojan; Shrestha, Sudhir; Varahramyan, Kody; Agarwal, Mangilal; Department of Mechanical Engineering, School of Engineering and Technology
    Paper-based batteries represent a new frontier in battery technology. However, low-flexibility and poor ionic conductivity of solid electrolytes have been major impediments in achieving practical mechanically flexible batteries. This work discuss new highly ionic conductive polymer gel electrolytes for paper-based battery applications. In this paper, we present a poly(vinylidene fluoride-hexafluoropropylene) (PVDH-HFP) porous membrane electrolyte enhanced with lithium bis(trifluoromethane sulphone)imide (LiTFSI) and lithium aluminum titanium phosphate (LATP), with an ionic conductivity of 2.1 × 10−3 S cm−1. Combining ceramic (LATP) with the gel structure of PVDF-HFP and LiTFSI ionic liquid harnesses benefits of ceramic and gel electrolytes in providing flexible electrolytes with a high ionic conductivity. In a flexibility test experiment, bending the polymer electrolyte at 90° for 20 times resulted in 14% decrease in ionic conductivity. Efforts to further improving the flexibility of the presented electrolyte are ongoing. Using this electrolyte, full-cell batteries with lithium titanium oxide (LTO) and lithium cobalt oxide (LCO) electrodes and (i) standard metallic current collectors and (ii) paper-based current collectors were fabricated and tested. The achieved specific capacities were (i) 123 mAh g−1 for standard metallic current collectors and (ii) 99.5 mAh g−1 for paper-based current collectors. Thus, the presented electrolyte has potential to become a viable candidate in paper-based and flexible battery applications. Fabrication methods, experimental procedures, and test results for the polymer gel electrolyte and batteries are presented and discussed.
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    Residential Emergency Backup Power Supply and Hazard Detector
    (2021-05-01) Medina, Marco; Izadian, Afshin
    The purpose of this device is to work as a power backup to a house’s sump pump system for when there is a power outage, specifically targeting homes older than the year 2000. It is assumed the UPS will be operating in a basement. The system will be able to operate continuously for 3 hours. If within this time, the battery is low, the pump overheats or fails to start, the client will receive an email notification. In addition, if the battery is bad and/or is not charging when the main AC power is back, the client will also get an email notification. Our UPS will contain the following components: a smart charger that will be connected to the main power source, an inverter that will convert DC to AC, and a bypass switch. Our system will have one current sensor, one voltage sensor, and an ultrasonic sensor. All the sensors will be connected to the embedded system. This will be key to keep our system working the way it should. The team will also keep in mind any standards that will apply to the system. They shall refer to IEEE, NEC, UL, IP Layer Protocol, and other agency standards with which to comply.