Browsing by Subject "Antarctica"
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Item Antarctica’s Dry Valleys: A potential source of soluble iron to the Southern Ocean?(AGU, 2015-03) Bhattachan, Abinash; Wang, Lixin; Miller, Molly F.; Licht, Kathy J.; D'Odorico, Paolo; Department of Earth Sciences, IU School of ScienceThe soluble iron content and dust emission potential of sediment samples collected from the Taylor Valley in the McMurdo Dry Valleys (MDVs) and sea ice in the McMurdo Sound were evaluated to determine whether inputs to the Southern Ocean may be sufficient to affect ocean productivity. Our results show that the dust-generating potential from the MDVs soils are comparable to those of sediments from other major dust sources in the Southern Hemisphere. Sediments from the MDVs and sea ice are one order of magnitude richer in soluble iron than those in other dust sources in the Southern Hemisphere. Forward trajectory analyses show that the dust from the MDVs is likely to be deposited in the Southern Ocean. These results provide evidence of the possible supply of soluble iron to the Southern Ocean associated with dust transport from the MDVs, should climate change expand the exposed areas of the continent.Item Chemical weathering signatures at Mt. Achernar, Central Transantarctic Mountains II: Surface exposed sediments(Elsevier, 2022-10-01) Graly, Joseph A.; Licht, Kathy J.; Bader, Nicole A.; Kassab, Christine M.; Bish, David L.; Kaplan, Michael R.; Earth and Environmental Sciences, School of ScienceMt Achernar Moraine is a high altitude, high latitude blue ice moraine where typical conditions preclude the presence of liquid water. Cosmogenic and salt accumulation dating indicate that the moraine’s surface is progressively older away from the active ice margin, with surface exposure ages up to 1 Ma. We analyze the chemical and mineralogical transformations in the <63 µm fraction along transects across the moraine. Data include bulk chemical composition, crystalline mineralogy by X-ray diffraction (XRD), and the composition of amorphous or low abundance products of chemical weathering by sequential extraction. These data are analyzed by multiple regression as a function of exposure age and as a function of composition of the moraine’s cobble and pebble-sized clasts. Change with exposure age is defined by the development of salts and carbonate minerals along with the input of detrital material, principally from sedimentary rocks. Clay minerals and amorphous cements breakdown as detrital material in proportions far above their abundance in the rock clasts, whereas framework silicates (i.e. feldspars and quartz) break down in relatively small proportions. Both the carbonate minerals and some of the salts form from atmospheric acids (i.e. H2CO3) that in turn react with other minerals. Mass balance shows that the input of these atmospheric acids balances with gains in authigenic smectites, zeolites, and amorphous material. Many of these minerals also form in the subglacial environment, but are poorly represented in the underlying rock, suggesting a similar chemical weathering regime in both the subglacial and surface environments of this hyper cold and arid setting. The rate of CO2 drawdown into carbonate minerals increases as the moraine progressively thickens, from 3 mg·m2·a−1 in freshly emerging sediments to ∼50 mg·m2·a−1 after 500 ka of exposure. Weathering from acidic aerosols is proportional to atmospheric flux documented in ice cores and does not vary with moraine thickness. The carbonate mineral formation rates are more than an order of magnitude below those of the subglacial environment and as much as two orders of magnitude below those found in warm desert soils. Nevertheless, the drawdown of atmospheric CO2 into carbonate minerals occurs in a terrestrial setting where water exists only in vapor form.Item Chemical weathering signatures from Mt. Achernar Moraine, Central Transantarctic Mountains I: Subglacial sediments compared with underlying rock(Elsevier, 2020-08) Graly, Joseph A.; Licht, Kathy J.; Bader, Nicole A.; Bish, David L.; Earth Sciences, School of ScienceIn order to determine chemical weathering rates on the subglacial land surface of Antarctica, we compare the composition and mineralogy of freshly emerging fine sediments to that of the underlying bedrock, as represented by glacially derived cobble-sized clasts. Samples were collected from Mt. Achernar Moraine, a large blue ice moraine, where subglacial material naturally emerges through sublimation of the surrounding ice. Both rocks and sediments were analyzed for total elemental composition, mineral abundance by X-ray diffraction, and by sequential extractions targeting chemical weathering products. The fine sediment fraction is significantly enriched in chemical weathering products and depleted in primary minerals compared with the cobble clasts. The alteration pathways consist primarily of the development of smectite, kaolinite, carbonate minerals, and amorphous material. Extensive Fe oxidation is evidenced by a decline in magnetic susceptibility and by increases in extractable Fe. If we assume the only input into the subglacial system is the water and ice-trapped gas supplied by basal melt, the net chemical alteration is explained through oxidation of organic matter equal to ∼0.7% of the bedrock mass and subsequent carbonation weathering. The underlying sedimentary rock is sufficiently rich in organic matter for this pathway to be plausible. For the O2 that is oxidizing organic matter to be supplied by basal meltwater, water fluxes would need to be three orders of magnitude larger than sediment fluxes. Independent models of basal melt and sediment transport at our field site confirm that such a difference between water and sediment flux is likely at the study site. The rate of subglacial carbonation weathering inferred from the Mt. Achernar Moraine site may be comparable to that found in high latitude subaerial environments. If Mt. Achernar Moraine is typical of other Antarctic sites, the subglacial land surface of Antarctica does play a role in global geochemical cycling.Item Double dating detrital zircons in till from the Ross Embayment, Antarctica(2014-05-21) Welke, Bethany Marie; Licht, Kathy J.; Hemming, Sidney R.; Martin, PamelaU/Pb and (U-Th)/He (ZHe) dating of detrital zircons from glacial till samples in the Ross Embayment, Antarctica records cooling after the Ross/Pan-African orogeny (450-625 Ma) followed by a mid-Jurassic to mid-Cretaceous heating event in the Beacon basin. Zircons were extracted from till samples from heads of major outlet glaciers in East Antarctica, one sample at the mouth of Scott Glacier, and from beneath three West Antarctic ice streams. The Ross/Pan-African U/Pb population is ubiquitous in these Antarctic tills and many Beacon Supergroup sandstones, thus 83 grains were analyzed for ZHe to subdivide this population. Two ZHe age populations are evident in East Antarctic tills, with 64% of grains 115-200 Ma and 35% between 200-650 Ma. The older population is interpreted to be associated with the Ross/Pan-African orogeny including cooling of the Granite Harbour Intrusives and/or exhumation of the older basement rocks to form the Kukri Peneplain. The lag time between zircon U/Pb, ZHe and 40Ar/39Ar ages from K-bearing minerals show cooling over 200 My. Grains in East Antarctic tills with a ZHe age of 115-200 Ma likely reflects regional heating following the breakup of Gondwana from the Ferrar dolerite intrusions, subsidence within the rift basin, and a higher geothermal gradient. Subsequent cooling and/or exhumation of the Transantarctic Mountains brought grains below the closure temperature over a span of 80 My. This population may also provide a Beacon Supergroup signature as most of the tills with this age are adjacent to nunataks mapped as Beacon Supergroup and contain an abundance of vi Beacon pebbles within the moraine. Nine zircons grains from three Beacon Supergroup sandstones collected from moraines across the Transantarctic Mountains yield ages from 125-180 Ma. West Antarctic tills contain a range of ZHe ages from 75-450 Ma reflecting the diverse provenance of basin fill from East Antarctica and Marie Byrd Land. ZHe and U/Pb ages <105 Ma appear to be distinctive of West Antarctic tills. The combination of U/Pb, ZHe and 40Ar/39Ar analyses demonstrates that these techniques can be used to better constrain the tectonic evolution and cooling of the inaccessible subglacial source terrains beneath the Antarctic Ice Sheet.Item The Dynamics of the Late Neogene Antarctic Ice Sheets in the Central Ross Sea using a Multianalytical Approach(2022-06) Mallery, Christopher Wallace; Licht, Kathy J.; Macris, Catherine A.; Gilhooly, William P. IIIWith the goal of determining ice sheet history in the central Ross Sea since the late Miocene, the provenance of glacial till from IODP expedition 374 site U1522 was assessed using a suite of three analyses. A total of 3,869 zircons, between 250-63 microns in size, from sixteen different cores were measured for U-Pb isotopes via LA-ICP-MS. Zircon data was compared to neodymium isotope and clast lithology datasets from collaborators. Site U1522 shows three distinct provenance shifts from the late Miocene to the Pleistocene, two of which are coincident with Ross Sea Unconformities three and two. Late Miocene samples have abundant Cretaceous zircon populations, radiogenic neodymium values, and clasts interpreted as having a West Antarctic provenance. In latest Miocene samples, zircons are mostly Ross Orogeny age (c. 470 615 Ma) and Cretaceous zircon grains are almost absent, neodymium values are relatively un radiogenic, and dolerite clasts are present signaling a shift to East Antarctic derived ice. Above Ross Sea Unconformity 3, early to mid Pliocene samples show a shift back to West Antarctic provenance with abundant Cretaceous zircons and more radiogenic neodymium values. Late Pliocene to Pleistocene samples, deposited above Ross Sea Unconformity 2, reflect dominant East Antarctic provenance with few Cretaceous zircon dates, relatively un radiogenic neodymium values, and the presence of dolerite clasts. These data are broadly in agreement with ice sheet interpretations suggested by clast analysis from ANDRILL site AND-1B. Permo-Triassic zircon dates suggest the presence of unexposed bedrock of this age beneath the West Antarctic Ice Sheet based on their association with Cretaceous dates that have not been reported from East Antarctica. The zircon dataset also reveals two late Miocene intervals with a previously undocumented Eocene Oligocene magmatic event ~30 40 Ma. The coexistence of Cretaceous dates in these intervals suggests a likely West Antarctic source. The absence of Eocene Oligocene zircons in subsequent Plio Pleistocene sediments may be explained by substantial erosion and offshore deposition of the West Antarctic interior, including volcanic edifices following the Middle Miocene Climatic Transition.Item Evidence for Extending Anomalous Miocene Volcanism at the Edge of the East Antarctic Craton(Wiley, 2018-04) Licht, Kathy J.; Groth, T.; Townsend, J. P.; Hennessy, Andrea J.; Hemming, S. R.; Flood, T. P.; Studinger, M.; Earth Sciences, School of ScienceUsing field observations followed by petrological, geochemical, geochronological, and geophysical data, we infer the presence of a previously unknown Miocene subglacial volcanic center ~230 km from the South Pole. Evidence of volcanism is from boulders of olivine‐bearing amygdaloidal/vesicular basalt and hyaloclastite deposited in a moraine in the southern Transantarctic Mountains. 40Ar/39Ar ages from five specimens plus U‐Pb ages of detrital zircon from glacial till indicate igneous activity 25–17 Ma. The likely source of the volcanism is a circular −735 nT magnetic anomaly 60 km upflow from the sampling site. Subaqueous textures of the volcanics indicate eruption beneath ice or into water at the margin of an ice mass during the early Miocene. These rocks record the southernmost Cenozoic volcanism in Antarctica and expand the known extent of the oldest lavas associated with West Antarctic Rift system. They may be an expression of lithospheric foundering beneath the southern Transantarctic Mountains.Item Meteoric 10Be as a Tracer for Subglacial Chemical Weathering in East Antarctica(2021-12) Arnardóttir, Eiríka Ösp; Licht, Kathy; Graly, Joseph; Bird, Broxton; Gilhooly, WilliamSubglacial chemical processes in Antarctica are potentially significant contributors to global geochemical cycles, but current understanding of their scale and nature is limited. A sequential chemical extraction procedure was developed and tested to investigate the utility of meteoric 10Be as a tracer for chemical weathering processes beneath the East Antarctic Ice Sheet. Subglacial meltwater is widely available under the Antarctic Ice Sheet and chemical constituents within it have the potential to drive geochemical weathering processes in the subglacial environment. Meteoric 10Be is a cosmogenic nuclide with a half-life of 1.39×106 years that is incorporated into glacier ice, therefore its abundance in the subglacial environment in Antarctica is meltwater dependent. It is known to adsorb to fine-grained particles in aqueous solution, precipitate with amorphous oxides, and/or be incorporated into authigenic clay structures during chemical weathering. The presence of 10Be in weathering products derived from beneath the ice therefore indicates chemical weathering processes in the subglacial environment. Freshly emerging subglacial sediments from the Mt. Achernar blue ice moraine were subject to chemical extractions where these weathering phases were isolated and 10Be concentrations therein quantified. Optimization of the phase isolation was developed by examining the effects of each extraction on the sample mineralogy and chemical composition. Experiments on 10Be desorption revealed that pH 3.2-3.5 was optimal for the extraction of adsorbed 10Be. Vigorous disaggregation of the samples before grain size separations and acid extractions is crucial due to the preferential fractionation of the nuclide with clay-sized particles. 10Be concentrations of 2-22×107 atoms g-1 measured in oxides and clay minerals in freshly emerging sediments strongly indicate subglacial chemical weathering in the catchment of the Mt. Achernar moraine. Sediment-meltwater contact in the system was calculated to be on the order of thousands of years, based on total 10Be sample concentrations, local basal melt rates, and 10Be ice concentrations. Strong correlation (R = 0.96) between 10Be and smectite abundance in the sediments indicate authigenic clay formation in the subglacial environment. This study shows that meteoric 10Be is a useful tool to characterize subglacial geochemical weathering processes under the Antarctic Ice Sheet.Item Polar desert chronologies through quantitative measurements of salt accumulation(Geological Society of America, 2018-02) Graly, Joseph A.; Licht, Kathy J.; Druschel, Gregory K.; Kaplan, Michael R.; Earth Sciences, School of ScienceWe measured salt concentration and speciation in the top horizons of moraine sediments from the Transantarctic Mountains (Antarctica) and compared the salt data to cosmogenic-nuclide exposure ages on the same moraine. Because the salts are primarily of atmospheric origin, and their delivery to the sediment is constant over relevant time scales, a linear rate of accumulation is expected. When salts are measured in a consistent grain-size fraction and at a consistent position within the soil column, a linear correlation between salt concentration and exposure age is evident. This correlation is strongest for boron-containing salts (R2 > 0.99), but is also strong (R2 ≈ 0.9) for most other water-extracted salt species. The relative mobility of salts in the soil column does not correspond to species solubility (borate is highly soluble). Instead, the highly consistent behavior of boron within the soil column is best explained by the extremely low vapor pressure of boric acid at cold temperatures. The environment is sufficiently dry that mobility of salt species within the soil column is controlled by vapor phase effects. In other cold desert settings, topsoil salts, specifically boron, may be employed as a proxy for relative sediment exposure age.Item Provenance Study of Reedy Glacier and West Antarctic Ice Stream Tills(2008-10-10T18:03:25Z) Kramer, Katie L.; Licht, Kathy J.; Swope, R. Jeffery; Barth, Andrew, 1958-In January 2007, 26 samples of till from 6 different moraines along the Reedy Glacier, East Antarctica were collected with the goal of differentiating between these samples and till collected from the base of the Whillans, Kamb, and Bindschadler Ice Streams of West Antarctica. The ability to differentiate between East and West Antarctic ice will allow us to constrain ice flow into the central Ross Sea during the Last Glacial Maximum (LGM), which has implications for more accurate reconstructions of the Ross Ice Sheet and its behavior. Moraines sampled from the head of Reedy Glacier give insight to the geology beneath the EAIS, and may be representative of what the glacier is eroding from its bed. Samples along the trunk of the glacier capture representative rock types eroded along the length of Reedy Glacier. At each moraine 3 replicate sub-sites were selected for collection to represent the diversity of material within each moraine. Comparisons are based on the composition of pebbles, particle size distributions, and sand petrography. Analysis of the pebble fraction shows that each sub-site contains similar rock types, however, the concentration of each rock type varies as much as 25-35%. Similar variation is also seen within the sub-site sand fraction. Both the pebble and sand fraction reflect the mapped bedrock geology. The dominant pebble types are coarse-grained felsic and intermediate igneous rocks, as well as quartzite. Similarly felsic igneous grains, quartzite, quartz, and feldspar characterize the sand fraction. Particle size analysis shows that v Reedy Glacier till averages 85% sand. The subglacial West Antarctic samples contain approximately 30% sand, and equal amounts of silt and clay, approximately 35% each. An observation of the sand fraction from beneath the West Antarctic Ice Streams shows composition similar to tills from Reedy Glacier. However, tills from the base of the West Antarctic Ice Streams contain up to 75% polymict grains, and in contrast, these grains are absent in the tills from Reedy Glacier. These sand-sized polymict grains dominate material from the base of Whillans and Bindschadler Ice Streams, whereas material from the base of Kamb Ice Stream contains grains of felsic igneous, quartz, feldspar, and few to no polymict grains. In addition to the polymict grains, the sand fraction in the ice stream cores contains trace fragments of sedimentary, and volcanic rocks, both of which are absent from the Reedy Glacier sand fraction. However, polymict grains are believed to represent a process occurring beneath the ice sheet, rather than indicate provenance. It is difficult to differentiate between the two tills, as both contain high concentrations of felsic-intermediate igneous lithics, quartz, and feldspar. The central Ross Sea contains sediment similar in rock type and mineralogy as seen within sediments from both Reedy Glacier, and the base of the ice streams of West Antarctica.Item RECONSTRUCTING PAST ANTARCTIC ICE FLOW PATHS IN THE ROSS EMBAYMENT, ANTARCTICA USING SAND PETROGRAPHY, PARTICLE SIZE AND DETRITAL ZIRCON PROVENANCE(2010-05-03T19:50:00Z) Schilling, Andrea J.; Licht, Kathy J.; Swope, R. Jeffery; Pachut, Joseph F., 1950-Tills for this study were analyzed from sites in East Antarctica (EA), West Antarctica (WA) and along a transect in the Ross Sea. Particle size, sand petrography, and detrital zircons were used to provide new information on the subglacial geology of Antarctica, as well as assisting in the reconstruction of Last Glacial Maximum (LGM) ice flow paths. Statistical analyses using the Kolmogorov-Smirnov (K-S test) reveal that EA and WA zircon age distributions are distinct at a P-value <0.05. This makes it possible to trace the unique signatures from EA and WA into the Ross Sea.