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Item An Analysis of Precipitation Isotope Distributions across Namibia Using Historical Data(Plos, 2016-05-04) Kaseke, Kudzai Farai; Wang, Lixin; Wanke, Heike; Turewicz, Veronika; Koeniger, Paul; Department of Earth Sciences, School of ScienceGlobal precipitation isoscapes based on the Global Network for Isotopes in Precipitation (GNIP) network are an important toolset that aid our understanding of global hydrologic cycles. Although the GNIP database is instrumental in developing global isoscapes, data coverage in some regions of hydrological interest (e.g., drylands) is low or non-existent thus the accuracy and relevance of global isoscapes to these regions is debatable. Capitalizing on existing literature isotope data, we generated rainfall isoscapes for Namibia (dryland) using the cokriging method and compared it to a globally fitted isoscape (GFI) downscaled to country level. Results showed weak correlation between observed and predicted isotope values in the GFI model (r2 < 0.20) while the cokriging isoscape showed stronger correlation (r2 = 0.67). The general trend of the local cokriging isoscape is consistent with synoptic weather systems (i.e., influences from Atlantic Ocean maritime vapour, Indian Ocean maritime vapour, Zaire Air Boundary, the Intertropical Convergence Zone and Tropical Temperate Troughs) and topography affecting the region. However, because we used the unweighted approach in this method, due to data scarcity, the absolute values could be improved in future studies. A comparison of local meteoric water lines (LMWL) constructed from the cokriging and GFI suggested that the GFI model still reflects the global average even when downscaled. The cokriging LMWL was however more consistent with expectations for an arid environment. The results indicate that although not ideal, for data deficient regions such as many drylands, the unweighted cokriging approach using historical local data can be an alternative approach to modelling rainfall isoscapes that are more relevant to the local conditions compared to using downscaled global isoscapes.Item Convergent vegetation fog and dew water use in the Namib Desert(Wiley, 2019) Wang, Lixin; Kaseke, Kudzai Farai; Ravi, Sujith; Jiao, Wenzhe; Mushi, Roland; Shuuya, Titus; Maggs-Kölling, Gillian; Earth Sciences, School of ScienceNonrainfall water inputs (e.g., fog and dew) are the least studied hydrological components in ecohydrology. The importance of nonrainfall waters on vegetation water status in arid ecosystems is receiving increasing attention. However, a clear understanding on how common plant water status benefits from nonrainfall waters, the impacts of different types of fog and dew events on vegetation water status, and the vegetation uptake mechanisms of nonrainfall waters is still lacking. In this study, we used concurrent leaf and soil water potential measurements from 3 years to investigate the species‐specific capacity to utilize moisture from fog and dew within the Namib Desert. Eight common plant species in the Namib Desert were selected. Our results showed that both fog and dew significantly increased soil water potential. Seven of the eight plant species studied responded to fog and dew events, although the magnitude of the response differed. Plants generally showed stronger responses to fog than to dew. Fog timing seemed to be an important factor determining vegetation response; for example, night fog did not affect plant water potential. We also found that Euclea pseudebenus and Faidherbia albida likely exploit fog moisture through foliar uptake. This study provides a first comprehensive assessment of the effects of nonrainfall waters on plant water status within the Namib Desert. Furthermore, this study highlights the importance of concurrent leaf and soil water potential measurements to identify the pathways of nonrainfall water use by desert vegetation. Our results fill a knowledge gap in dryland ecohydrology and have important implications for other drylands.Item Ecohydrological interactions within “fairy circles” in the Namib Desert: Revisiting the self-organization hypothesis(Wiley, 2017-02) Ravi, Sujith; Wang, Lixin; Kaseke, Kudzai Farai; Buynevich, Ilya V.; Marais, Eugene; Earth Science, School of ScienceVegetation patterns such as rings, bands, and spots are recurrent characteristics of resource-limited arid and semiarid ecosystems. One of the most recognizable vegetation patterns is the millions of circular patches, often referred to as “fairy circles,” within the arid grassland matrix extending over hundreds of kilometers in the Namib Desert. Several modeling studies have highlighted the role of plant-soil interactions in the formation of these fairy circles. However, little is known about the spatial and temporal variabilities of hydrological processes inside a fairy circle. In particular, a detailed field assessment of hydrological and soil properties inside and outside the fairy circles is limited. We conducted extensive measurements of infiltration rate, soil moisture, grass biometric, and sediment grain-size distribution from multiple circles and interspaces in the Namib Desert. Our results indicate that considerable heterogeneity in hydrological processes exists within the fairy circles, resulting from the presence of coarser particles in the inner bare soil areas, whereas concentration of fine soil occurs on the vegetated edges. The trapping of aeolian and water-borne sediments by plants may result in the observed soil textural changes beneath the vegetation, which in turn, explains the heterogeneity in hydrological processes such as infiltration and runoff. Our investigation provides new insights and experimental data on the ecohydrological processes associated with fairy circles, from a less studied location devoid of sand termite activity within the circles. The results seem to provide support to the “self-organization hypothesis” of fairy circle formation attributed to the antiphase spatial biomass-water distributions.Item Fog Spatial Distributions over the Central Namib Desert - An Isotope Approach(2018) Kaseke, Kudzai Farai; Tian, Chao; Wang, Lixin; Seely, Mary; Vogt, Roland; Wassenaar, Theo; Mushi, Roland; Earth Sciences, School of ScienceFog is a characteristic feature of the Namib Desert and is essential to life in this fog dependent system. It is often acknowledged that advective fog from the ocean is the dominant fog type over the Namib Desert fog-zone but recent evidence suggests that other fog types occur in this area. Knowledge of the existence and spatial distribution of different fog types will enhance the mechanistic understanding of fog formation and potential changes in this region, but such knowledge is limited in literature. In this study, we investigated fog spatial variations within the Namib Desert fog-zone by applying stable isotope (δ18O and δ2H) techniques to differentiate various fog types and identify their source waters. Isotope based results showed that at least three types of fog (advective, radiation and mixed) occurred in this region and what appears as a single fog event may include all three types. Results suggest that radiation fog was the dominant fog type during our study period. The results also suggest that advective fog (with Atlantic Ocean origins) either dissipated 30–50 km inland and the residual humidity combined with locally derived moisture to form mixed fog or advective fog incorporated local moisture along its trajectory inland resulting in mixed fog. Fog in the Namib Desert was consistently depleted in 18O and 2H compared to rainfall and this was attributed to sub-cloud evaporation of the rainfall as well as different sources of fog and rainfall. Sub-cloud evaporation led to enrichment of 18O and 2H in rainfall beyond that of the first stage condensate, fog. Advective fog is often considered the architect of the fog-zone in the Namib Desert, but our results demonstrated multiple dominant fog types during the study period, suggesting knowledge of both fog frequency and fog type is needed to better predict climate change impacts on the fog-zone.Item Investigating the role of evaporation in dew formation under different climates using 17O-excess(Elsevier, 2021-01) Tian, Chao; Jiao, Wenzhe; Beysens, Daniel; Kaseke, Kudzai Farai; Medici, Marie-Gabrielle; Li, Fadong; Wang, Lixin; Earth Sciences, School of ScienceWith increasing aridity in many regions, dew is likely to play an increasingly important role in the ecohydrological processes in many ecosystems, especially in arid and semiarid regions. Few studies investigated the role of evaporation during dew formation and how it varies under different climate settings. 17O-excess, as a new tracer, could be used to extract information of evaporation dynamics from natural water samples (e.g., precipitation, river, and lake). Therefore, to fill the knowledge gap in evaporation mechanisms during dew formation, we report the isotopic variation (δ2H, δ18O, δ17O, and 17O-excess) of dew and precipitation from three distinct climatic regions (i.e., Gobabeb in the central Namib Desert, Nice in France with Mediterranean climate, and Indianapolis in the central United States with humid continental climate). We examined whether dew formed in different climate settings was affected by different degree of evaporation using observed isotopic values and evaporation models during the formation processes, and modeled the effects of key meteorological variables (i.e., temperature and relative humidity) on 17O-excess variations. The results showed that dew in Gobabeb experienced kinetic fractionation associated with evaporation under non-steady state conditions during dew formation with enriched δ18O and low 17O-excess values. Dew formations with temperatures over 14.7 °C in Indianapolis were also influenced by evaporation under non-steady state conditions. However, dew formation in Nice did not experience significant evaporation. Evaporation processes (equilibrium or kinetic fractionation) occurring during nights with heavy dew under three climate settings were mainly related to the variation of atmosphere relative humidity. The 17O-excess tracer provides a new method to distinguish the different evaporation processes (equilibrium or kinetic fractionation) during dew formation and our result provides an improved understanding of dew formation.Item Nonrainfall water origins and formation mechanisms(AAAS, 2017-03-01) Kaseke, Kudzai Farai; Wang, Lixin; Seely, Mary K.; Department of Earth Sciences, School of ScienceDryland ecosystems cover 40% of the total land surface on Earth and are defined broadly as zones where precipitation is considerably less than the potential evapotranspiration. Nonrainfall waters (for example, fog and dew) are the least-studied and least-characterized components of the hydrological cycle, although they supply critical amounts of water for dryland ecosystems. The sources of nonrainfall waters are largely unknown for most systems. In addition, most field and modeling studies tend to consider all nonrainfall inputs as a single category because of technical constraints, which hinders prediction of dryland responses to future warming conditions. This study uses multiple stable isotopes (2H, 18O, and 17O) to show that fog and dew have multiple origins and that groundwater in drylands can be recycled via evapotranspiration and redistributed to the upper soil profile as nonrainfall water. Surprisingly, the non–ocean-derived (locally generated) fog accounts for more than half of the total fog events, suggesting a potential shift from advection-dominated fog to radiation-dominated fog in the fog zone of the Namib Desert. This shift will have implications on the flora and fauna distribution in this fog-dependent system. We also demonstrate that fog and dew can be differentiated on the basis of the dominant fractionation (equilibrium and kinetic) processes during their formation using the 17O-18O relationship. Our results are of great significance in an era of global climate change where the importance of nonrainfall water increases because rainfall is predicted to decline in many dryland ecosystems. Fog and dew in the Namib Desert have multiple origins and their formation can be differentiated using stable isotopes. Fog and dew in the Namib Desert have multiple origins and their formation can be differentiated using stable isotopes.Item Precipitation Origins and Key Drivers of Precipitation Isotope (18O, 2H, and 17O) Compositions Over Windhoek(AGU, 2018) Kaseke, Kudzai Farai; Wang, Lixin; Wanke, Heike; Tian, Chao; Lanning, Matthew; Jiao, Wenzhe; Earth Sciences, School of ScienceSouthern African climate is characterized by large precipitation variability, and model precipitation estimates can vary by 70% during summer. This may be partly attributed to underestimation and lack of knowledge of the exact influence of the Atlantic Ocean on precipitation over the region. The current study models trajectories of precipitation events sampled from Windhoek (2012–2016), coupled with isotopes (δ18O, δ2H, δ17O, d, and δ′17O‐δ′18O) to determine key local drivers of isotope compositions as well as infer source evaporative conditions. Multiple linear regression analyses suggest that key drivers of isotope compositions (relative humidity, precipitation amount, and air temperature) account for 47–53% of δ18O, δ2H, and δ17O variability. Surprisingly, precipitation δ18O, δ2H, and δ17O were independent of precipitation type (stratiform versus convective), and this may be attributed to greater modification of stratiform compared to convective raindrops, leading to convergence of isotopes from these precipitation types. Trajectory analyses showed that 78% and 21% of precipitation events during the period originated from the Indian and South Atlantic Oceans, respectively. Although precipitation from the Atlantic Ocean was significantly enriched compared to that from the Indian Ocean (p < 0.05), d was similar, suggesting significant local modification (up to 55% of d variability). Therefore, d may not be a conservative tracer of evaporation conditions at the source, at least for Windhoek. The δ′17O‐δ′18O appeared to be a better alternative to d, consistent with trajectory analyses, and appeared to differentiate El Niño from non‐El Niño droughts. Thus, δ′17O‐δ′18O could be a novel tool to identify drought mechanisms.Item Reconciling the isotope-based fog classification with meteorological conditions of different fog types(Elsevier, 2022-02) Kaseke, Kudzai Farai; Wang, Lixin; Earth Sciences, School of ScienceAlthough fog is an important component of the hydrological cycle of drylands, its formation mechanisms are not fully understood leading to discrepancy of fog type classifications using different methodologies. Such discrepancies may result in under or over estimation of the potential impacts of global climate change on the ecohydrology of fog dependent ecosystems. To fill this knowledge gap, this study applies hydrogen and oxygen stable isotopes to objectively classify fog and compares this classification to meteorological conditions defined for the formation of these fog types. Results suggest that this isotope based fog classification method is consistent with expected meteorological conditions for the different fog types such as radiation fog, advection fog and mixed fog. Wind speeds decreased from advection, to radiation fog while estimated fog (cloud) height was lowest during radiation fog and highest during advection fog. In addition, precipitation-offset (lc-excess) suggests that radiation and advection fog had different moisture sources, with radiation fog being locally sourced and advection fog originating from the ocean. This study suggests isotope-based fog classification is an objective method that could be applied to other coastal fog dependent ecosystems to help assess the potential impact of climate change on these ecosystems.Item A Stable Isotope Approach to Investigative Ecohydrological Processes in Namibia(2018-12) Kaseke, Kudzai Farai; Wang, Lixin; Jacinthe, Pierre Andre; Gilhooly, William P.; Wilson, Jeffrey; Soderberg, KeirDrylands cover 40% of the earth’s terrestrial surface supporting over 2 billion people, the majority of whom reside in developing nations characterised by high population growth rates. This imposes pressure on the already limited water resources and in some dryland regions such as southern Africa, the origins and dynamics of rainfall are not well understood. Research has also tended to focus on factors limiting (e.g., rainfall) than sustaining productivity in drylands. However, non-rainfall water (NRW) e.g., fog and dew can supplement and/or exceed rainfall in these environments and could potentially be exploited as potable water resources. Much remains unknown in terms of NRW formation mechanisms, origins, evolution, potability and potential impact of global climate change on these NRW dependent ecosystems. Using Namibia as a proxy for drylands and developing nations, this dissertation applies stable isotopes of water (δ2H, δ18O, δ17O and d-excess), cokriging and trajectory analysis methods to understand ecohydrological processes. Results suggest that locally generated NRW may be a regular occurrence even in coastal areas such as the Namib Desert, and that what may appear as a single fog event may consist of different fog types co-occurring. These results are important because NRW responses to global climate change is dependent on the source, groundwater vs. ocean, and being able to distinguish the two will allow for more accurate modelling. I also demonstrate, that fog and dew formation are controlled by different fractionation processes, paving the way for plant water use strategy studies and modelling responses to global climate change. The study also suggests that current NRW harvesting technologies could be improved and that the potability of this water could raise some public health concerns related to trace metal and biological contamination. At the same time, the dissertation concludes that global precipitation isoscapes do not capture local isotope variations in Namibia, suggesting caution when applied to drylands and developing nations. Finally, the dissertation also reports for the first time, δ17O precipitation results for Namibia, novel isotope methods to differentiate synoptic from local droughts and suggests non-negligible moisture contributions from the Atlantic Ocean due to a possible sub-tropical Atlantic Ocean dipole.Item Stable isotope compositions (δ2H, δ18O and δ17O) of rainfall and snowfall in the central United States(Nature Publishing group, 2018-04-30) Tian, Chao; Wang, Lixin; Kaseke, Kudzai Farai; Bird, Broxton W.; Earth Science, School of ScienceStable isotopes of hydrogen and oxygen (δ2H, δ18O and δ17O) can be used as natural tracers to improve our understanding of hydrological and meteorological processes. Studies of precipitation isotopes, especially 17O-excess observations, are extremely limited in the mid-latitudes. To fill this knowledge gap, we measured δ2H, δ18O and δ17O of event-based precipitation samples collected from Indianapolis, Indiana, USA over two years and investigated the influence of meteorological factors on precipitation isotope variations. The results showed that the daily temperature played a major role in controlling the isotope variations. Precipitation experienced kinetic fractionation associated with evaporation at the moisture source in the spring and summer and for rainfall, while snowfall, as well as precipitation in the fall and winter, were mainly affected by equilibrium fractionation. The 17O-excess of both rainfall and snowfall were not affected by local meteorological factors over the whole study period. At the seasonal scale, it was the case only for the spring. Therefore, 17O-excess of rainfall, snowfall and the spring precipitation could be considered as tracers of evaporative conditions at the moisture source. This study provides a unique precipitation isotope dataset for mid-latitudes and provides a more mechanistic understanding of precipitation formation mechanisms in this region.