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Browsing by Author "Gilhooly, William"
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Item Meteoric 10Be as a Tracer for Subglacial Chemical Weathering in East Antarctica(2021-12) Arnardóttir, Eiríka Ösp; Licht, Kathy; Graly, Joseph; Bird, Broxton; Gilhooly, WilliamSubglacial chemical processes in Antarctica are potentially significant contributors to global geochemical cycles, but current understanding of their scale and nature is limited. A sequential chemical extraction procedure was developed and tested to investigate the utility of meteoric 10Be as a tracer for chemical weathering processes beneath the East Antarctic Ice Sheet. Subglacial meltwater is widely available under the Antarctic Ice Sheet and chemical constituents within it have the potential to drive geochemical weathering processes in the subglacial environment. Meteoric 10Be is a cosmogenic nuclide with a half-life of 1.39×106 years that is incorporated into glacier ice, therefore its abundance in the subglacial environment in Antarctica is meltwater dependent. It is known to adsorb to fine-grained particles in aqueous solution, precipitate with amorphous oxides, and/or be incorporated into authigenic clay structures during chemical weathering. The presence of 10Be in weathering products derived from beneath the ice therefore indicates chemical weathering processes in the subglacial environment. Freshly emerging subglacial sediments from the Mt. Achernar blue ice moraine were subject to chemical extractions where these weathering phases were isolated and 10Be concentrations therein quantified. Optimization of the phase isolation was developed by examining the effects of each extraction on the sample mineralogy and chemical composition. Experiments on 10Be desorption revealed that pH 3.2-3.5 was optimal for the extraction of adsorbed 10Be. Vigorous disaggregation of the samples before grain size separations and acid extractions is crucial due to the preferential fractionation of the nuclide with clay-sized particles. 10Be concentrations of 2-22×107 atoms g-1 measured in oxides and clay minerals in freshly emerging sediments strongly indicate subglacial chemical weathering in the catchment of the Mt. Achernar moraine. Sediment-meltwater contact in the system was calculated to be on the order of thousands of years, based on total 10Be sample concentrations, local basal melt rates, and 10Be ice concentrations. Strong correlation (R = 0.96) between 10Be and smectite abundance in the sediments indicate authigenic clay formation in the subglacial environment. This study shows that meteoric 10Be is a useful tool to characterize subglacial geochemical weathering processes under the Antarctic Ice Sheet.Item Reconstructing Holocene Indian Summer Monsoon Variability Using High Resolution Sediments from the Southeastern Tibet(2020-12) Perello, Melanie Marie; Bird, Broxton; Gilhooly, William; Filippelli, Gabriel; Wang, Lixin; Wilson, JeffreyThe Indian summer monsoon (ISM) is the dominant hydrometeorological phenomenon that provides the majority of precipitation to southern Asia and southeastern Tibet specifically. Reliable projections of ISM rainfall are critical for water management and hinge on our understanding of the drivers of the monsoon system and how these drivers will be impacted by climate change. Because instrumental climate records are limited in space and time, natural climate archives are required to understand how the ISM varied in the past in response to changes in climatic boundary climate conditions. Lake sediments are high-resolution natural paleoclimate archive that are widely distributed across the Tibetan Plateau, making them useful for investigating long-term precipitation trends and their response to climatic boundary conditions. To investigate changes in monsoon intensity during the Holocene, three lakes were sampled along an east-west transect in southeastern Tibet: Galang Co, Nir’Pa Co, and Cuobu. Paleoclimate records from each lake were developed using isotopic (leaf wax hydrogen isotopes; δ2H), sedimentological, and geochemical proxies of precipitation and lake levels. Sediments were sampled at high temporal frequencies, with most proxies resolved at decadal scales, to capture multi-decadal to millennial-scale variability in monsoon intensity and local hydroclimate conditions. The ISM was strongest in the early Holocene as evidenced by leaf-wax n-alkane δ2H at both Cuobu and Galang Co corresponding with Cuobu’s higher lake levels and effective moisture. Monsoon intensity declined at Cuobu and Galang Co around 6 ka which corresponds to reduced riverine sediment influxes at Cuobu and deeper lake levels at Galang Co. The antiphase relationship between lake levels and monsoon intensity at Galang Co is attributed to air temperatures and effective moisture, with a warmer and drier local hydroclimate driving early Holocene low lake levels. The late Holocene ISM was more variable with wet and dry periods, as seen in the Nir’Pa Co lake level and leaf wax n-alkane δ2H record. These records demonstrate coherent drivers of synoptic and local hydroclimate that account for Holocene ISM expression across the southeastern Tibetan Plateau, indicating possible drivers of future monsoon expression under climate change.