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Item A global synthesis of transpiration rate and evapotranspiration partitioning in the shrub ecosystems(Elsevier, 2022-03) Gao, Guangyao; Wang, Di; Zha, Tianshan; Wang, Lixin; Fu, Bojie; Earth and Environmental Sciences, School of ScienceTranspiration (T) is a fundamental process in understanding the ecophysiology of plants, and it is the dominant component of evapotranspiration (ET) in the terrestrial water cycle. Although previous studies have examined T characteristics of shrub ecosystems in some regions, global-scale synthesis that integrates the spatial variations of T, ET and ratio of T to ET (T/ET) and the associated influences of bio-/abiotic factors in the shrub ecosystems is currently lacking. In this study, we synthesized and analyzed T rate, ET rate and T/ET of the shrub ecosystems from the peer-reviewed articles using field observations around the world. These studies were mainly distributed in drylands with aridity index (ratio of precipitation to potential ET) < 0.65, which accounted for 86.4% of the study locations. Globally, the mean daily T and ET rates of shrubs were 1.5 ± 1.0 mm d−1 and 2.4 ± 0.8 mm d−1, with coefficient of variation of 63.2% and 36.2% among the study locations, respectively. Mean T/ET of the shrubs over the growing season was 0.54 ± 0.14, which was generally lower compared with forest, grassland and cropland ecosystems. The T rate of shrubs was positively related to shrub age, shrub height, leaf area index, and vegetation coverage (p < 0.05), and the effects of biotic factors on T rate were stronger compared with abiotic factors. The ET rate of shrubs was positively related to aridity index, long-term annual mean precipitation, mean soil water content, as well as shrub height and vegetation coverage (p < 0.05). By contrast, the effects of biotic factors on variations of shrub T/ET were weaker than those of abiotic factors, and the T/ET of shrubs was negatively related to aridity index, long-term annual mean precipitation and mean soil water content, but positively related to latitude (p < 0.05). This study is an important supplement of our knowledge gap in terrestrial water cycle, and the findings suggest that T accounted for about half of the water into atmosphere from shrub ecosystems, and the variations of T rate of shrubs were mainly controlled by biotic factors, whereas ET rate and T/ET was mainly affected by abiotic factors.Item A Landsat-derived annual inland water clarity dataset of China between 1984 and 2018(Copernicus, 2022-01-13) Tao, Hui; Song, Kaishan; Liu, Ge; Wang, Qiang; Wen, Zhidan; Jacinthe, Pierre-Andre; Xu, Xiaofeng; Du, Jia; Shang, Yingxin; Li, Sijia; Wang, Zongming; Lyu, Lili; Hou, Junbin; Wang, Xiang; Liu, Dong; Shi, Kun; Zhang, Baohua; Duan, Hongtao; Earth and Environmental Sciences, School of ScienceWater clarity serves as a sensitive tool for understanding the spatial pattern and historical trend in lakes' trophic status. Despite the wide availability of remotely sensed data, this metric has not been fully explored for long-term environmental monitoring. To this end, we utilized Landsat top-of-atmosphere reflectance products within Google Earth Engine in the period 1984–2018 to retrieve the average Secchi disk depth (SDD) for each lake in each year. Three SDD datasets were used for model calibration and validation from different field campaigns mainly conducted during 2004–2018. The red blue band ratio algorithm was applied to map SDD for lakes (>0.01 km2) based on the first SDD dataset, where R2=0.79 and relative RMSE (rRMSE) =61.9 %. The other two datasets were used to validate the temporal transferability of the SDD estimation model, which confirmed the stable performance of the model. The spatiotemporal dynamics of SDD were analyzed at the five lake regions and individual lake scales, and the average, changing trend, lake number and area, and spatial distribution of lake SDDs across China were presented. In 2018, we found the number of lakes with SDD <2 m accounted for the largest proportion (80.93 %) of the total lakes, but the total areas of lakes with SDD of <0.5 and >4 m were the largest, both accounting for about 24.00 % of the total lakes. During 1984–2018, lakes in the Tibetan–Qinghai Plateau region (TQR) had the clearest water with an average value of 3.32±0.38 m, while that in the northeastern region (NLR) exhibited the lowest SDD (mean 0.60±0.09 m). Among the 10 814 lakes with SDD results for more than 10 years, 55.42 % and 3.49 % of lakes experienced significant increasing and decreasing trends, respectively. At the five lake regions, except for the Inner Mongolia–Xinjiang region (MXR), more than half of the total lakes in every other region exhibited significant increasing trends. In the eastern region (ELR), NLR and Yungui Plateau region (YGR), almost more than 50 % of the lakes that displayed increase or decrease in SDD were mainly distributed in the area range of 0.01–1 km2, whereas those in the TQR and MXR were primarily concentrated in large lakes (>10 km2). Spatially, lakes located in the plateau regions generally exhibited higher SDD than those situated in the flat plain regions. The dataset is freely available at the National Tibetan Plateau Data Center (https://doi.org/10.11888/Hydro.tpdc.271571, Tao et al., 2021).Item Appearance of an enigmatic Pb source in South America around 2000 BP: Anthropogenic vs natural origin(Elsevier, 2020-05) Kamenov, George D.; Escobar, Jaime; Arnold, T. Elliott; Pardo-Trujillo, Andrés; Gangoiti, Gotzon; Hoyos, Natalia; Curtis, Jason H.; Bird, Broxton W.; Velez, Maria Isabel; Vallejo, Felipe; Trejos-Tamayo, Raul; Earth and Environmental Sciences, School of ScienceNeotropical wetlands in the paramo (a unique alpine-tundra ecosystem) region of South America have the potential to be natural archives for metal pollution by modern and past populations. An organic-rich sediment core from the El Triunfo mire, located in the paramo region, provides a record of natural and anthropogenic metal sources in the Northern Andes during the last four millennia. The Triunfo record is complex, as the mire is located in the Northern Volcanic Zone (NVZ) and receives direct input of volcanic material. Regardless of the volcanic input, calculated metal enrichment factors normalized to Sc show metal enrichment in the Northern Andes around 2000 years ago and again in recent industrial times. A number of samples show a shift to lower Pb isotope ratios indicating the appearance of a new, enigmatic Pb source around 2000 years ago. The topmost layer of the core shows the lowest Pb isotope ratios, reflecting input of modern anthropogenic Pb. In contrast to Pb, Nd isotopes do not show significant variations along the entire core, indicating mostly volcanic material input to the mire. The decoupling between Nd and Pb isotopes indicates that the enigmatic Pb source must be anthropogenic in origin. Based on the dominant atmospheric currents in the region, the El Triunfo mire can receive input from long-distance and local sources. Dispersion simulations validate the possibility of pollutant particle transport from Europe to the northern hemisphere Neotropics. As the first metal enrichment coincides with the Roman Empire times, the El Triunfo Pb isotopes are compared to contemporary peat records from Europe. All records show similar decrease in the Pb isotope ratios due to anthropogenic Pb input. Small Pb isotope differences between a record from Spain and El Triunfo indicate that the enigmatic Pb that appeared around 2000 years ago in the mire is unlikely to have originated from long-distance Roman Empire pollution. Instead, a group of deposits, namely San Lucas, San Martin de Loba, and El Bagre, located in north-central Colombia, show low Pb isotope ratios that can potentially explain the observed Pb signal in the El Triunfo sediments. The deposits are located up wind, along the predominant atmospheric currents in the region. Therefore, it is plausible that mining activities in the area of San-Lucas, San-Martin, and/or El Bagre released Pb in the atmosphere that was transported and deposited in the El Triunfo mire. These deposits are not associated with the known regions of influence of any of the early pre-Hispanic cultures in Colombia and there is no evidence for mining in this region around 2000 years ago. However, given that all other possibilities are unlikely, the appearance of lower Pb isotope ratios in the mire suggests the onset of mining in the region at least 400 years earlier than the available archaeological evidence at present. The El Triunfo mire record can be used as indirect evidence for significant metal exploitation by early pre-Hispanic cultures in the northern Andes as early as 2000 years ago.Item Application of Scenario Earthquakes for Analysis of Seismically Triggered Landslide Hazard: A Case Study in Costa Rica(Central American School of Geology, University of Costa Rica, 2022-07-11) Seal , Dylan M.; Nowicki Jessee, M. Anna; Hamburger, Michael W.; Ruiz , Paulo; Earth and Environmental Sciences, School of ScienceIn this study, we demonstrate the capabilities of hypothetical scenario earthquakes as a new tool for assessment of hazards associated with earthquake-triggered landslides. Costa Rica offers an ideal environment for demonstrating the utility of scenario earthquakes due to its diverse tectonic environments and associated widespread seismic hazard, rugged topography, and high landslide susceptibility. We investigate the relative influence of landslide proxies such as topographic slope, peak ground velocity (PGV), and compound topographic index (CTI), and earthquake source parameters such as magnitude and depth, on predicted landslide probability and fatality. We examine five distinct tectonic environments, including subduction events beneath the (1) Nicoya and (2) Osa peninsulas respectively, (3) intraplate earthquakes beneath the Central Volcanic Range (CVR) and (4) the Central Costa Rica Deformed Belt (CCRDB), and (5) back-arc thrust events on the eastern Caribbean coast. Our results demonstrate that the slope, PGV, and CTI thresholds necessary to produce landslide probabilities greater than 10% vary by tectonic environment. In all cases, we observe magnitude to be the primary control on the predicted maximum landslide probability and overall areal landslide coverage. We validate model predictions with observed landslide inventories from the 2009 Cinchona and 1991 Limon earthquakes, demonstrating a good fit, where over 70% of landslides occurring in zones of greater than 20% probability. We also use a global model of landslide impact to predict exposure and fatality ranges for each scenario earthquake of this study, revealing that moderate-sized earthquakes in the CCRDB and CVR and large subduction megathrust earthquakes each pose a significant hazard to Costa Rica’s population.Item Assessing Unequal Airborne Exposure to Lead Associated With Race in the USA(Wiley, 2023-07-24) Laidlaw, Mark A. S.; Mielke, Howard W.; Filippelli, Gabriel M.; Earth and Environmental Sciences, School of ScienceRecent research applied the United States Environmental Protection Agency's Chemical Speciation Network and Interagency Monitoring of Protected Visual Environments monitoring stations and observed that mean concentrations of atmospheric lead (Pb) in highly segregated counties are a factor of 5 higher than in well‐integrated counties and argument is made that regulation of existing airborne Pb emissions will reduce children's Pb exposure. We argue that one of the main sources of children's current Pb exposure is from resuspension of legacy Pb in soil dust and that the racial disparity of Pb exposure is associated with Pb‐contaminated community soils.Item Assessing variability of optimum air temperature for photosynthesis across site-years, sites and biomes and their effects on photosynthesis estimation(Elsevier, 2021) Chang, Qing; Xiao, Xiangming; Doughty, Russell; Wu, Xiaocui; Jiao, Wenzhe; Qin, Yuanwei; Earth and Environmental Sciences, School of ScienceGross primary productivity (GPP) of vegetation is affected by air temperature. Biogeochemical models use the optimum air temperature (Topt) parameter, which comes from biome-specific look-up tables (Topt−b−LT). Many studies have shown that plants have the capacity to adapt to changes in environmental conditions over time, which suggests that the static Topt−b−LT parameters in the biogeochemical models may poorly represent actual Topt and induce uncertainty in GPP estimates. Here, we estimated biome-specific, site-year-specific, and site-specific optimum air temperature using GPP data from eddy covariance (EC) flux tower sites (GPPEC) (Topt−b−EC, Topt−sy−EC, Topt−s−EC), the Enhanced Vegetation Index (EVI) from MODIS images (Topt−b−EVI, Topt−sy−EVI, Topt−s−EVI), and mean daytime air temperature (TDT). We evaluated the consistency among the four Topt parameters (Topt−b, Topt−sy, Topt−s and Topt−b−LT), and assessed how they affect satellite-based GPP estimates. We find that Topt parameters from MODIS EVI agree well with those from GPPEC, which indicates that EVI can be used as a variable to estimate Topt at individual pixels over large spatial domains. Topt−b, Topt−sy, and Topt−s differed significantly from Topt−b−LT. GPP estimates using Topt−b and Topt−sy were more consistent with GPPEC than when using Topt−b−LT for all the land cover types. Our use of Topt−sy substantially improved 8-day and annual GPP estimates across biomess (from 1% to 34%), especially for cropland, grassland, and open shrubland. Our simple calculation shows that global GPP estimates differ by up to 10 Pg C/yr when using our suggested Topt−sy−EVI instead of using the static Topt−b−LT. Our new approach on estimating Topt has the potential to improve estimates of GPP from satellite-based models, which could lead to better understanding of carbon-climate interactions.Item Carbon and Phosphorus Cycling in Arabian Sea Sediments across the Oxygen Minimum Zone(Longdom Publishing, 2017-11-09) Filippelli, Gabriel M.; Cowie, Gregory L.; Earth and Environmental Sciences, School of ScienceSeveral studies have focused on carbon, oxygen, and phosphorus dynamics across the modern oxygen minimum zone (OMZ) to constrain how signals of modern systems get “locked in” upon burial. In this study, a sequential phosphorus fractionation technique was applied to surficial and sub-surface sediments from stations at depths spanning the OMZ on the Pakistan margin of the Arabian Sea in order to test the oxygen-carbon-phosphorus connection in modern marine sediments. Some early diagenetic loss of phosphorus compared to organic carbon was observed, but a significant portion of the released phosphorus was retained by uptake on oxyhydroxides and by the formation of an authigenic phosphorus-bearing phase. This process is unaffected by station location relative to the OMZ, and results in an effective organic carbon-to-reactive-phosphorus sediment ratio that is close to the average observed for open-ocean sediments, regardless of bottom water oxygen content.Item Contrasting water use characteristics of riparian trees under different water tables along a losing river(Elsevier, 2022-08) Li, Yue; Ma, Ying; Song, Xianfang; Wang, Lixin; Yang, Lihu; Li, Xiaoyan; Li, Binghua; Earth and Environmental Sciences, School of ScienceRivers losing flow into surrounding aquifers (‘losing’ rivers) are common under changing climates and groundwater overexploitation. The riparian plant-water relations under various water table dynamics along a losing river remain unclear. In this study, the water isotopes (δ2H and δ18O), leaf δ13C, and MixSIAR model were used combinedly for determining the root water uptake patterns and leaf water use efficiency (WUE) of Salix babylonica (L.) at three sites (A, B, and C) with different water table depths (WTDs) in the riparian zone of Jian and Chaobai River in Beijing, China. The correlations of water source contributions with WTD and WUE were quantified. The riparian S. babylonica primarily took up upper (0–80 cm) soil water (71.5%) with the lowest leaf δ13C (−28.8 ± 1.1 ‰) at site A under deep WTD (20.5 ± 0.5 m). In contrast, deep water below 80 cm depth including groundwater contributed 55.1% to S. babylonica at site B with fluctuated shallow WTD (1.9 ± 0.4 m), where leaf δ13C was highest (−27.9 ± 1.0 ‰). The S. babylonica mainly used soil water in 30–170 cm layer (56.9%) with mean leaf δ13C of − 28.2 ‰ ± 0.7 ‰ at site C with stable shallow WTD (1.5 ± 0.1 m). It was found that both the contributions of upper soil water in 0–80 cm and deep water below 80 cm had significantly quadratic correlations with WTD under shallow water table conditions (p < 0.05). Leaf δ13C was negatively correlated with contributions of upper soil water above 80 cm depth, but it was positively related to the contributions of deep water below 80 cm in linear functions (p < 0.001). The results indicated that 2.1 m was the optimum WTD for riparian trees, because they maximized the use of deep water sources to get the highest WUE. This study provides insights into managing groundwater, surface water resources and riparian afforestation in losing rivers.Item Contributory science reveals insights into metal pollution trends across different households and environmental media(IOP, 2023-02-17) Dietrich, Matthew; Wood, Leah R.; Shukle, John T.; Herrmann, Angela; Filippelli, Gabriel M.; Earth and Environmental Sciences, School of ScienceHeavy metals are prevalent in urban settings due to many legacy and modern pollution sources, and are essential to quantify because of the adverse health effects associated with them. Of particular importance is lead (Pb), because there is no safe level of exposure, and it especially harms children. Through our partnership with community scientists in the Marion County (Indiana, United States) area (n = 162 households), we measured Pb and other heavy metal concentrations in soil, paint, and dust. Community scientists completed sampling with screening kits and samples were analyzed in the laboratory via x-ray fluorescence by researchers to quantify heavy metal concentrations, with Pb hazards reported back to participants. Results point to renters being significantly (p ≤ 0.05) more likely to contain higher concentrations of Pb, zinc (Zn), and copper (Cu) in their soil versus homeowners, irrespective of soil sampling location at the home. Housing age was significantly negatively correlated with Pb and Zn in soil and Pb in dust across all homes. Analysis of paired soil, dust, and paint samples revealed several important relationships such as significant positive correlations between indoor vacuum dust Pb, dust wipe Pb, and outdoor soil Pb. Our collective results point to rental status being an important determinant of metal pollution exposure in Indianapolis, with housing age being reflective of both past and present Zn and Pb pollution at the household scale in dust and soil. Thus, future environmental pollution work examining renters versus homeowners, as well as other household data such as home condition and resident race/ethnicity, is imperative for better understanding environmental disparities surrounding not just Pb, but other heavy metals in environmental media as well.Item Current and future carbon stocks of natural forests in China(Elsevier, 2022-05-01) Chen, Shiyin; Lu, Nan; Fu, Bojie; Wang, Shuai; Deng, Lei; Wang, Lixin; Earth and Environmental Sciences, School of ScienceNatural regeneration of forests is the most cost-effective and most technically straightforward strategy to mitigate climate change. Natural forests account for 71% of China’s forested area, but their carbon stocks and sequestration potentials remain unclear. Here, we compiled data from 762 natural forest sites across China and found that natural forests had a carbon stock of 9.40 ± 1.45 Pg C in 2010. When naturally regenerated to the over-mature stage, existing natural forests can additionally sequestrate 8.67 ± 6.93 Pg C in the next two centuries, accounting for 48% of the carbon carrying capacity of the natural forest ecosystem in China, i.e. 18.07 ± 6.78 Pg C. Future carbon sequestration potential in natural forests is dominated by the tree layer at 6.88 ± 6.87 Pg, followed by the shrub layer at 1.02 ± 0.55 Pg, floor layer at 0.72 ± 0.74 Pg and herb layer at 0.05 ± 0.10 Pg. The natural forests are expected to achieve 70% of their future carbon sequestration potential by 2100. We also note that assisted regeneration via tree planting can play a significant role in natural forest restoration, as the carbon densities of natural and planted forests are rarely significantly different at the same age under 60 years old. Therefore, the preservation and expansion of natural forests is the key strategy for achieving long-term carbon sequestration.