Browsing by Author "Shukle, John T."
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Item Author Correction: Unraveling iron oxides as abiotic catalysts of organic phosphorus recycling in soil and sediment matrices(Springer Nature, 2024-08-30) Basinski, Jade J.; Bone, Sharon E.; Klein, Annaleise R.; Thongsomboon, Wiriya; Mitchell, Valerie; Shukle, John T.; Druschel, Gregory K.; Thompson, Aaron; Aristilde, Ludmilla; Earth and Environmental Sciences, School of ScienceCorrection to: Nature Communications 10.1038/s41467-024-47931-z, published online 18 July 2024 The original version of this Article contained an error in the Abstract, which was previously incorrectly given as ‘ten-fold’. The correct version states ‘twenty-fold’ in place of ‘ten-fold’. This has been corrected in both the PDF and HTML versions of the Article.Item Contributory science reveals insights into metal pollution trends across different households and environmental media(IOP, 2023-02-17) Dietrich, Matthew; Wood, Leah R.; Shukle, John T.; Herrmann, Angela; Filippelli, Gabriel M.; Earth and Environmental Sciences, School of ScienceHeavy metals are prevalent in urban settings due to many legacy and modern pollution sources, and are essential to quantify because of the adverse health effects associated with them. Of particular importance is lead (Pb), because there is no safe level of exposure, and it especially harms children. Through our partnership with community scientists in the Marion County (Indiana, United States) area (n = 162 households), we measured Pb and other heavy metal concentrations in soil, paint, and dust. Community scientists completed sampling with screening kits and samples were analyzed in the laboratory via x-ray fluorescence by researchers to quantify heavy metal concentrations, with Pb hazards reported back to participants. Results point to renters being significantly (p ≤ 0.05) more likely to contain higher concentrations of Pb, zinc (Zn), and copper (Cu) in their soil versus homeowners, irrespective of soil sampling location at the home. Housing age was significantly negatively correlated with Pb and Zn in soil and Pb in dust across all homes. Analysis of paired soil, dust, and paint samples revealed several important relationships such as significant positive correlations between indoor vacuum dust Pb, dust wipe Pb, and outdoor soil Pb. Our collective results point to rental status being an important determinant of metal pollution exposure in Indianapolis, with housing age being reflective of both past and present Zn and Pb pollution at the household scale in dust and soil. Thus, future environmental pollution work examining renters versus homeowners, as well as other household data such as home condition and resident race/ethnicity, is imperative for better understanding environmental disparities surrounding not just Pb, but other heavy metals in environmental media as well.Item Generation of Silicic Melts in the Early Izu-Bonin Arc Recorded by Detrital Zircons in Proximal Arc Volcaniclastic Rocks From the Philippine Sea(Wiley, 2017) Barth, Andrew P.; Tani, K.; Meffre, S.; Wooden, J. L.; Coble, M. A.; Arculus, R. J.; Ishizuka, O.; Shukle, John T.; Department of Earth Sciences, School of ScienceA 1.2 km thick Paleogene volcaniclastic section at International Ocean Discovery Program Site 351-U1438 preserves the deep-marine, proximal record of Izu-Bonin oceanic arc initiation, and volcano evolution along the Kyushu-Palau Ridge (KPR). Pb/U ages and trace element compositions of zircons recovered from volcaniclastic sandstones preserve a remarkable temporal record of juvenile island arc evolution. Pb/U ages ranging from 43 to 27 Ma are compatible with provenance in one or more active arc edifices of the northern KPR. The abundances of selected trace elements with high concentrations provide insight into the genesis of U1438 detrital zircon host melts, and represent useful indicators of both short and long-term variations in melt compositions in arc settings. The Site U1438 zircons span the compositional range between zircons from mid-ocean ridge gabbros and zircons from relatively enriched continental arcs, as predicted for melts in a primitive oceanic arc setting derived from a highly depleted mantle source. Melt zircon saturation temperatures and Ti-in-zircon thermometry suggest a provenance in relatively cool and silicic melts that evolved toward more Th and U-rich compositions with time. Th, U, and light rare earth element enrichments beginning about 35 Ma are consistent with detrital zircons recording development of regional arc asymmetry and selective trace element-enriched rear arc silicic melts as the juvenile Izu-Bonin arc evolved.Item International Analysis of Sources and Human Health Risk Associated with Trace Metal Contaminants in Residential Indoor Dust(ACS, 2021-12) Isley, Cynthia Faye; Fry, Kara L.; Liu, Xiaochi; Filippelli, Gabriel Michael; Entwistle, Jane A.; Martin, Adam P.; Kah, Melanie; Meza-Figueroa, Diana; Shukle, John T.; Jabeen, Khadija; Famuyiwa, Abimbola O.; Wu, Liqin; Sharifi-Soltani, Neda; Doyi, Israel N. Y.; Argyraki, Ariadne; Ho, Kin Fai; Dong, Chenyin; Gunkel-Grillon, Peggy; Aelion, C. Marjorie; Taylor, Mark Patrick; Earth Sciences, School of SciencePeople spend increasing amounts of time at home, yet the indoor home environment remains understudied in terms of potential exposure to toxic trace metals. We evaluated trace metal (and metalloid) concentrations (As, Cu, Cr, Mn, Ni, Pb, and Zn) and health risks in indoor dust from homes from 35 countries, along with a suite of potentially contributory residential characteristics. The objective was to determine trace metal source inputs and home environment conditions associated with increasing exposure risk across a range of international communities. For all countries, enrichments compared to global crustal values were Zn > Pb > Cu > As > Cr > Ni; with the greatest health risk from Cr, followed by As > Pb > Mn > Cu > Ni > Zn. Three main indoor dust sources were identified, with a Pb–Zn–As factor related to legacy Pb sources, a Zn–Cu factor reflecting building materials, and a Mn factor indicative of natural soil sources. Increasing home age was associated with greater Pb and As concentrations (5.0 and 0.48 mg/kg per year of home age, respectively), as were peeling paint and garden access. Therefore, these factors form important considerations for the development of evidence-based management strategies to reduce potential risks posed by indoor house dust. Recent findings indicate neurocognitive effects from low concentrations of metal exposures; hence, an understanding of the home exposome is vital.Item Predictive modeling of indoor dust lead concentrations: Sources, risks, and benefits of intervention(Elsevier, 2023) Dietrich, Matthew; Barlow, Cynthia F.; Entwistle, Jane A.; Meza-Figueroa, Diana; Dong, Chenyin; Gunkel-Grillon, Peggy; Jabeen, Khadija; Bramwell, Lindsay; Shukle, John T.; Wood, Leah R.; Naidu, Ravi; Fry, Kara; Taylor, Mark Patrick; Filippelli, Gabriel M.; Earth and Environmental Sciences, School of ScienceLead (Pb) contamination continues to contribute to world-wide morbidity in all countries, particularly low- and middle-income countries. Despite its continued widespread adverse effects on global populations, particularly children, accurate prediction of elevated household dust Pb and the potential implications of simple, low-cost household interventions at national and global scales have been lacking. A global dataset (∼40 countries, n = 1951) of community sourced household dust samples were used to predict whether indoor dust was elevated in Pb, expanding on recent work in the United States (U.S.). Binned housing age category alone was a significant (p < 0.01) predictor of elevated dust Pb, but only generated effective predictive accuracy for England and Australia (sensitivity of ∼80%), similar to previous results in the U.S. This likely reflects comparable Pb pollution legacies between these three countries, particularly with residential Pb paint. The heterogeneity associated with Pb pollution at a global scale complicates the predictive accuracy of our model, which is lower for countries outside England, the U.S., and Australia. This is likely due to differing environmental Pb regulations, sources, and the paucity of dust samples available outside of these three countries. In England, the U.S., and Australia, simple, low-cost household intervention strategies such as vacuuming and wet mopping could conservatively save 70 billion USD within a four-year period based on our model. Globally, up to 1.68 trillion USD could be saved with improved predictive modeling and primary intervention to reduce harmful exposure to Pb dust sources.Item The impact of combined sewer outflows on urban water quality: Spatio-temporal patterns of fecal coliform in indianapolis(Elsevier, 2023) Orr, Isheka; Mazari, Katerina; Shukle, John T.; Li, Rui; Filippelli, Gabriel M.; Earth and Environmental Sciences, School of ScienceMany urban waterways with older stormwater drainage systems receive a significant amount of untreated or poorly treated waste from Combined Sewer Outflow (CSO) systems during precipitation events. The input of effluent waste from CSO to urban water streams during storm events often leads to elevated fecal coliform, specifically Escherichia Coli (E. Coli) in these waterways. The aim of the study is to examine fecal coliform concentration, water chemistry, and water quality parameters to better understand spatio-temporal patterns of fecal coliform associated with CSO events in three waterways from Indianapolis, Indiana (USA). The waterways are Pleasant Run Creek (PRW), Fall Creek (FC) and White River (WR). The sampling occurred biweekly over one year for PRW, nine months for FC, and an intense (∼every three days) sub-analysis of the presumed peak period of fecal coliform growth (July) for WR. All PRW and FC sampling sites significantly exceeded the EPA contact standard limit of 200 CFU/100 mL for fecal coliform concentrations during the sampling period. We found no relationship between fecal coliform levels and the number or density of CSO outfalls above a given site. The most significant predictors of increased fecal coliform concentrations were precipitation on the sampling day and cumulative degree days. The most significant predictors of decreased fecal coliform were maximum precipitation during the ten-day window prior to sampling and median discharge during a three-day window prior to sampling. These findings suggest a push-pull balance within the system where CSO activation and seasonal gradients replenish and promote fecal coliform growth. At the same time, large hydrologic events act to flush and dilute fecal coliform concentrations. The results from this study help us to better understand how different drivers influence fecal coliform growth and how this information can be potentially used to predict and remediate the conditions of urban water streams.Item Unraveling iron oxides as abiotic catalysts of organic phosphorus recycling in soil and sediment matrices(Springer Nature, 2024-07-18) Basinski, Jade J.; Bone, Sharon E.; Klein, Annaleise R.; Thongsomboon, Wiriya; Mitchell, Valerie; Shukle, John T.; Druschel, Gregory K.; Thompson, Aaron; Aristilde, Ludmilla; Earth and Environmental Sciences, School of ScienceIn biogeochemical phosphorus cycling, iron oxide minerals are acknowledged as strong adsorbents of inorganic and organic phosphorus. Dephosphorylation of organic phosphorus is attributed only to biological processes, but iron oxides could also catalyze this reaction. Evidence of this abiotic catalysis has relied on monitoring products in solution, thereby ignoring iron oxides as both catalysts and adsorbents. Here we apply high-resolution mass spectrometry and X-ray absorption spectroscopy to characterize dissolved and particulate phosphorus species, respectively. In soil and sediment samples reacted with ribonucleotides, we uncover the abiotic production of particulate inorganic phosphate associated specifically with iron oxides. Reactions of various organic phosphorus compounds with the different minerals identified in the environmental samples reveal up to ten-fold greater catalytic reactivities with iron oxides than with silicate and aluminosilicate minerals. Importantly, accounting for inorganic phosphate both in solution and mineral-bound, the dephosphorylarion rates of iron oxides were within reported enzymatic rates in soils. Our findings thus imply a missing abiotic axiom for organic phosphorus mineralization in phosphorus cycling.Item Using Community Science to Better Understand Lead Exposure Risks(AGU, 2022-02) Dietrich, Matthew; Shukle, John T.; Krekeler, Mark P. S.; Wood, Leah R.; Filippelli, Gabriel M.; Earth Sciences, School of ScienceLead (Pb) is a neurotoxicant that particularly harms young children. Urban environments are often plagued with elevated Pb in soils and dusts, posing a health exposure risk from inhalation and ingestion of these contaminated media. Thus, a better understanding of where to prioritize risk screening and intervention is paramount from a public health perspective. We have synthesized a large national data set of Pb concentrations in household dusts from across the United States (U.S.), part of a community science initiative called “DustSafe.” Using these results, we have developed a straightforward logistic regression model that correctly predicts whether Pb is elevated (>80 ppm) or low (<80 ppm) in household dusts 75% of the time. Additionally, our model estimated 18% false negatives for elevated Pb, displaying that there was a low probability of elevated Pb in homes being misclassified. Our model uses only variables of approximate housing age and whether there is peeling paint in the interior of the home, illustrating how a simple and successful Pb predictive model can be generated if researchers ask the right screening questions. Scanning electron microscopy supports a common presence of Pb paint in several dust samples with elevated bulk Pb concentrations, which explains the predictive power of housing age and peeling paint in the model. This model was also implemented into an interactive mobile app that aims to increase community-wide participation with Pb household screening. The app will hopefully provide greater awareness of Pb risks and a highly efficient way to begin mitigation.