Ascenzi-Pettenuzzo, CristinaNganda, JulietDeng, Yongming2024-12-042024-12-042023-11Ascenzi-Pettenuzzo, C., Nganda, J., & Deng, Y. (2023). Photoinduced Pyridine N-oxides Catalyzed Carbon Radical Generation from Alkylboronic Acids. ChemCatChem, 15(22), e202300953. https://doi.org/10.1002/cctc.202300953https://hdl.handle.net/1805/44764Herein we report a protocol for the generation of alkyl carbon radicals from alkylboronic acids wherein photoexcited 4-nitropyridine N-oxide biradical features a catalyst to promote the nucleo-homolytic substitution of boronic acids. With a wide range of readily available aliphatic boronic acids, including methyl boronic acid, the developed catalytic system demonstrates broad applicability for alkylation, amination, and cyanation.enAttribution-NonCommercial 4.0 Internationalpyridine N-oxidecarbon radicalboronic acidArticle