Miao, JinminFang, PingJagdeep, SahotaGe, Haibo2017-09-282017-09-282016-02Miao, J., Fang, P., Jagdeep, S., & Ge, H. (2016). Palladium-catalyzed decarboxylative alkoxycarbonylation of potassium aryltrifluoroborates with potassium oxalate monoesters. Organic Chemistry Frontiers, 3(2), 243–250. https://doi.org/10.1039/C5QO00349Khttps://hdl.handle.net/1805/14203Palladium-catalyzed decarboxylative alkoxycarbonylation of potassium aryltrifluoroborates with potassium oxalate monoesters in the presence of potassium persulfate was performed under mild conditions. A number of benzoyl esters with a wide variety of substituents at different positions were efficiently synthesized with this method. Mechanism of the palladium-catalyzed decarboxylative carbonylation of aryltrifluoroborates was studied, and a radical-mediated Pd(II)/Pd(IV) catalytic cycle was proposed.enPublisher Policypalladium-catalyzed decarboxylative alkoxycarbonylationpotassium aryltrifluoroboratespotassium oxalate monoestersArticle